Technology for extracting zinc from metallurgical waste (冶金废料锌提取技术)
Technology for extracting zinc from waste from the metallurgical industry.
The waste from processing scrap steel in smelting furnaces is dust (Welz-sublimation) in (~30 kg per 1 ton of steel). Dust composition up to 40% Zn (ZnO) and ferrite, as well as oxides of Fe, Pb and other metals. The world stock of waste is > 5 billion tons.
Zinc extraction steps
- 1) leaching of sublimate in NaOH or NH4Cl solution;
- 2) cleaning the solution from Pb(II) ions by contact displacement with zinc;
- 3) electrodeposition of Zn on steel (graphite anodes, alkaline or ammonium chloride electrolyte with a developed package of additives for high deposition rates and obtaining a compact deposit).
Technical characteristics of the zinc electrodeposition process:
- -Current density 5−6 A/dm2;
- -Electrolyte temperature 65−70 °C;
- -Electrolytes are stable and easy to adjust;
- -Deposition rate 85−100 µm/h;
- -Zn content in the cathode deposit ≥ 98 wt. %;
- -Specific electricity consumption 3000 kW∙h/t;
- -Zinc current output 92−97%;
- -Closed cycle;
- -The coating is compact, easily separated from the steel;
- -There is no or minimized chlorine release.
Leaflet in CHINESE (传单)