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Oleg Ivashkevich

EN | RU

Chief Researcher
Doctor of Sciences (Chemistry)
Academician of the National Academy of Sciences of Belarus
Honored Staff Member of the Belarusian State University
Laureate of the State Prize in Science and Technology
Honored Scientist of the Republic of Belarus

Department: Laboratory for chemistry of condensed systems
e-mail: ivashkevicho@bsu.by
Phone: +375 (17) 209-50-29

  • h-индекс (Scopus) – 26
  • h-индекс (Web of Science) – 18

Subject and Class of Degrees
1976 – BSU, Faculty of Chemistry;
1982 – Ph.D (in chemistry), BSU;
1998 – Doctor of Sciences (Chemistry), BSU.

Career
1976–1983 – Engineer, Senior Engineer, Jr. Researcher, Applied Chemistry Sector, NIO BSU;
1984–1987 – Leading Researcher, Laboratory of General Chemistry, NIO BSU;
1988–1993 – Head of the Research Laboratory of General Chemistry, NIO BSU;
1993–1997 – deputy. Director for Research, RI PCP BSU;
1997–2009 – Director of the RI PHP BSU;
2009–2015 – Vice-rector for scientific work of BSU;
2015–2019 – first vice-rector of BSU;
2020 – now – Chief Researcher, Laboratory of Condensed Matter Chemistry, RI PHP BSU.
 
Awards

  • "Honored Scientist of the Republic of Belarus", 2016
  • "Honored Worker of the Belarusian State University", 2013
  • Laureate of the State Prize of the Republic of Belarus in the field of science and technology, 2013
  • Honorary Doctor of the Siberian Branch of the Russian Academy of Sciences, 2012
  • Academician of the National Academy of Sciences of Belarus, 2009
  • Awarded with the Francysk Skaryna Medal, 2009
  • Corresponding Member of the National Academy of Sciences of Belarus, 2004.

Current research activity

  • physical chemistry of the processes of thermal decomposition and combustion of condensed systems;
  • physicochemistry of azoles;
  • applied quantum chemistry.

 Main achievements

Simple and effective methods and technologies of obtaining a number of tetrazole-containing polymers by polymer-analogous transformations of polyacrylonitrile together with prof. P.N. Gaponik have been developed. The industrial production of these tetrazole-containing polymers was created.

Studies of the kinetics and mechanism of thermal decomposition of tetrazole and a number of its derivatives have been studied. Wide range of polyvinyltetrazoles with substituents of various nature in the cycle have been created. A new generation of components and formulations of compositions for energy devices used in special technology have been developed together with Academician of the National Academy of Sciences of Belarus A.I. Lesnikovich. 

A new type of combustion, called liquid-flame combustion, has been discovered and investigated.

A new semiempirical exchange-correlation functional of electron density has been developed, intended for studying the structure and properties of small clusters of transition metals. It was used for the first time to reliably identify the spatial structure of a number of anionic clusters of silver, copper and binary silver-copper clusters.

In recent years, under the leadership of O.A. Ivashkevich carried out a series of studies aimed at developing synthesis methods, studying the structure, physicochemical properties and biological activity of complex compounds of biogenic metals with nitrogen-containing heterocyclic ligands and identified a number of compounds with high antitumor activity in combination with relatively low toxicity.

O.A. Ivashkevich is the author of about 500 scientific papers, as well as 49 copyright certificates and patents, textbooks "Applied Quantum Chemistry" and "Structure of Matter" with the stamp of the Ministry of Education for chemical specialties of universities of the Republic of Belarus, as well as the monograph "New compounds and materials based on micro- and nanoscale particles: production, properties, application ”(based on the materials of the cycle of works awarded the State Prize of the Republic of Belarus in the field of science and technology in 2013). Prepared 2 doctors and 5 candidates of chemical sciences.

 List of Selected Publications:

  1. Voitekhovich S.V, Lyakhov A.S., ShimanD.I., Grigoriev Y.V., Ivashkevich L.S., Klose J., Kersting B., Ivashkevich O.A. 1,3-Bis(1-methyl-1H-tetrazol-5-yl)propane and its coordination polymers with Сu2Cl4 and Сu3Cl6 units // Polyhedron. 2020. Vol. 190. 114793.  https://doi.org/10.1016/j.poly.2020.114793 (IF 2.343)
  2. Fedotov А.К., Prischepa S.L., Fedotova J.A., Bayev V.G., Ali Arash Ronassi, Komissarov I.V., Kovalchuk N.G., Vorobyova S.A., IvashkevichO.A. Electrical conductivity and magnetoresistance in twisted graphene electrochemically decorated with Co particles Physica E: Low-Dimensional Systems and Nanostructures. 2020. Vol. 117. 113790.  https://doi.org/10.1016/j.physe.2019.113790 (IF 3.176)
  3. Matulis V.E., Ragoyja, E.G., Ivashkevich O.A. Accurate theoretical prediction of optical properties of BODIPY dyes // International Journal of Quantum Chemistry. 2020. Vol. 120. e26159https://doi.org/10.1002/qua.26159 (IF 2.263)
  4. Voitekhovich S.V, Degtyarik M.M., Lyakhov A.S., Ivashkevich L.S., Klose J., Kersting B., Ivashkevich O.A. Halido-bridged Copper(II) Complexes with 1-tert-Butyl-1H-tetrazole: Crystal Structure and Magnetic Properties // Zeitschrift für Anorganische und Allgemeine Chemie. 2020. Vol. 646. Р. 1331–1335.  https://doi.org/10.1002/zaac.202000225  (IF 1.270)
  5. Voitekhovich S.V, Grigoriev Y.V., Lyakhov A.S., Matulis V.E., Ivashkevich L.S., Bogomyakov A.S., Lavrenova L.G., Ivashkevich O.A. 1-(1,2,4-Triazol-3-yl)-1H-tetrazoles and their complexation with copper(II) chloride // Polyhedron. 2020. Vol. 176. 114299 .https://doi.org/10.1016/j.poly.2019.114299 (IF 2.343)
  6. Voitekhovich S.V., Lyakhov A.S., Ivashkevich L.S., Ivashkevich O.A. Copper-assisted Desulfurization of 1-R-Tetrazole-5-Tioles under Complexatio 2/343)n // Inorganic Chemistry Communication. 2020. Vol. 114. 107827. https://doi.org/10.1016/j.inoche.2020.107827 (IF 1.795).
  7. Voitekhovich S.V., Grigoriev Y.V., Lyakhov A.S., Matulis V.E., Ivashkevich L.S., Ivashkevich O.A. 2-(1H-Tetrazol-1-yl)thiazole: сomplexation and copper-assisted tetrazole ring transformation// Polyhedron. 2019. Vol. 171. P. 423–432.  https://doi.org/10.1016/j.poly.2019.07.030  (IF 2.343)
  8. Voitekhovich S.V., Lyakhov A.S., Matulis V.E., Ivashkevich L.S., Ivashkevich O.A. Substituent-dependent coordination modes of 1-methyl-5-R-tetrazoles // Polyhedron. 2019. Vol. 162. P. 100–110  https://doi.org/10.1016/j.poly.2019.01.009  (IF 2.343)
  9. Semak I.V, Budzevich A., Maluyshkova E., Kuzniatsova V., Popkov N., Zalutsky I., Ivashkevich O. Large-Scale Production of Biologically Active Recombinant Human Lactoferrine by a Heard of Transgenic Goats // Transgenic Research. 2019. Vol. 28. Issue 5-6. P. 465-478. https://doi.org/10.1007/s11248-019-00165-y  (IF 1.817)
  10. Brinkevich S.D., Maliborskii A.Ya., Kapusto I.A., Sverdlov R.L., Grigoriev Y.V., Ivashkevich O.A., Shadyro O.I. Interaction of 1,2,4-triazole Nitro Derivatives with α-Hydroxylethyl Radicals: A Steady-State Radiolysis Study // High Energy Chemistry. 2019. Vol. 53. № 2.  P. 147-154. https://doi.org/10.1134/S0018143919020036 (IF 0.738)  
  11. Bisballe N., Hedidi M., Demmer C.S., Chevallier F., Roisnel T., Dorcet V., Halauko Y.S., Ivashkevich O.A., Matulis Vadim E., Bentabed-Ababsa G., Bunch L., Mongin F. Functionalization of Oxazolo[4,5-b]pyrazines by Deprotometallation // European Journal of Organic Chemistry. 2018. P. 3904–3913.
  12. Voitekhovich S.V., Mosalkova A.P., Lyakhov A.S., Ivashkevich L.S.,  Schmorl S., Kersting B., Ivashkevich O.A. Selective Synthesis and Complexation of Novel JV,JV-Alkylene-Bridged Bis(5-pyridyltetrazole) // Z. Anorg. Allg. Chem. 2018. Vol. 644. P. 1611-1617. https://doi.org/10.1002/zaac.201800242  (IF 1.179)
  13. Bayev V.G., Fedotova J.A., Vorobyova S.A., Sviti I.A., Ivashkevich O.A., Tyutyunnikov S.I., Kolobylina N.N., Guryeva P.V. Mössbauer spectroscopy and magnetometry of FeCo-Ag and FeCo-Au nanocomposites synthesized by a redox-transmetalation method // Materials Chemistry and Physics. 2018. Vol. 216. P. 349–353.
  14. Samovich S.N., Sverdlov R.L., Voitekhovich S.V., Grigoriev Y.V., Ivashkevich O.A., Shadyro O.I. Effects of quinones and azoles on radiation-induced processes involving hydroxyl-containing carbon-centered radicals // Radiation Physics and Chemistry. 2018. Vol. 144. P. 308-316.
  15. Zuraev A.V., Grigoriev Y.V., Budevich V.A., Ivashkevich O. A. Copper-polymer nanocomposite: An efficient catalyst for green Huisgen click synthesis // Tetrahedron Letters. 2018. Vol. 59. No 16. P. 1583–1586.
  16. Bayev V.G., Fedotova J.A., Kasiuk J.V., Vorobyova S.A., Sohor A.A., Komissarov I.V., Kovalchuk N.G., Prischepa S.L., KarginN.I., Andrulevicius M., Przewozni J., Kapusta Cz., Ivashkevich O.A., Tyutyunnikov S.I., Kolobylina N.N.  Guryeva P.V. CVD graphene sheets electrochemically decorated with "core-shell" Co/CoO nanoparticles // Applied Surface Science. 2018. Vol.440. P. 1252–1260.
  17. Tazi M., Hedidi M., Erb W., Halauko Y.S., Ivashkevich O.A., Matulis Vadim E., Roisnel T., Dorcet V., Bentabed-Ababsa G., Mongin F. Fluoro- and Chloroferrocene: From 2- to 3-Substituted Derivatives // Organometallics. 2018. Vol. 37. P. 2207−2211.
  18. Voitekhovich S.V., Lyakhov A.S., Ivashkevich L.S., Schmorl S., Kersting B. Ivashkevich O.A. The first characterized coordination compounds of macrocyclic ligands including incorporated tetrazole rings // Crystal Growth & Design. 2017. Vol. 17. Р. 1796–1805.
  19. Tazi M., Erb M., Halauko Y.S., Ivashkevich O.A., Matulis V.E., Roisnel T., Dorcet V., Mongin F. From 2- to 3-Substituted Ferrocene Carboxamides or How to Apply Halogen “Dance” to the Ferrocene Series // Organometallics. 2017. Vol. 36. P. 4770–4778.
  20. Hedidi M., Maillard J., Erb W., Lassagne F., Halauko Y. S., Ivashkevich O.A., Matulis V.E., Roisnel T., Dorcet V., Hamzé M., Fajloun Z., Baratte B., Ruchaud S., Bach S., Bentabed-Ababsa G., Mongin F. Fused Systems Based on 2-Aminopyrimidines: Synthesis Combining Deprotolithiation-in situ Zincation with N-Arylation Reactions and Biological Properties // European Journal of Organic Chemistry. 2017. P. 5903–5915.
  21. Hedidi M., Erb W., Lassagne F., Halauko Y.S., Ivashkevich O.A., Matulis Vad.E., Roisnel T., Bentabed-Ababsa G., Mongin F.  Functionalization of pyridyl ketones using deprotolithiation – in situ zincation // RCS Advances. 2016. Vol. 6. P. 63185–63189.
  22. Marquise N., Chevallier F., Nassar E., Frederich M., Ledoux A., Halauko Y., Ivashkevich O., Matulis V.E., Roisnel T., Mongin F. Substituted azafluorenones: access from dihalogeno diaryl ketones by palladium-catalyzed auto-tandem process and evaluation of their antibacterial, antifungal, antimalarial and antiproliferative activities // Tetrahedron. 2016. Vol. 72. P. 825–836.
  23. Hedidi M., Bentabed-Ababsa G., Derdour A., Halauko Y., Ivashkevich O., Matulis V.E., Chevallier F., Roisnel T., Dorcet V., Mongin F. Deprotometalation of Substituted Pyridines and Regioselectivity-Computed CH-Acidity Relationship // Tetrahedron. 2016. Vol. 72. P. 2196-2205.
  24. Jeremis A., Lehmann U., Gruschinski S., Matulis V.E., Ivashkevich O., Jäsсhke A., Kersting B. Synthesis, Structures, Electrochemistry and Magnetic Properties of Face-Sharing Bioctahedral Nickel Complexes Containing a N3Ni(μ-S2)(μ-X)NiN3 Core (X=F, Cl, Br, N3, OH) // Journal of Organometallic Chemistry. 2016. Vol. 821. Р. 171–181.
  25. Jeremis A., Gruschinski S., Meyer M., Matulis Vit. E., Ivashkevich O.,Kobalz K., Kersting K. Azide Binding Controlled by Steric Interactions in Second Sphere. Syntheses, Crystal Structure, and magnetic Properties of [NiII2(L1)(μ1,1-N3][ClO4] // Inorganic Chemistry. 2016. Vol. 55. P. 1843–1853.
  26. Voitekhovich S.V., Grigoriev Y.V., Lyakhov A.S., Ivashkevich L.S., Ivashkevich O.A. The first organocopper tetrazole derivative: synthesis and characterization // Dalton Transactions. 2016. Vol. 45. Р. 13406–13414.
  27. Degtyarik M.М., Lyakhov A.S., Ivashkevich L.S., Matulis V.E., Matulis V.E., Gruschinski S., Voitekhovich S.V., Kersting B., Ivashkevich O.A. Copper(II) tetrafluoroborate complexes with the N3,N4-bridging coordination of 1-(tert-butyl)-1H-tetrazole: synthesis, crystal structure and magnetic properties // Dalton Transactions. 2015. Vol. 44. Р. 18518–18526.
  28. Jeremies A., Lehmann U., Gruschinski S., Schleife F, Meyer M., Matulis V., Ivashkevich O.A., Handke M., Stein K., Kersting B. Cavitands Incorporating a Lewis Acid Dinickel Chelate Function as Receptors for Halide Anions // Inorganic Chemistry. 2015. Vol. 54. P. 3937–3950.
  29. Messaoud M.Y.A., Bentabed-Ababsa G., Hedidi M., Derdour A., Chevallier F., Halauko Y.S., Ivashkevich O.A., Matulis V.E., Picot L., Thiéry V., Roisnel T., Dorcet V., Mongin F. Deproto-metallation of N-arylated pyrroles and indoles using a mixed lithium–zinc base and regioselectivity-computed CH acidity relationship // Beilstein Journal of Organic Chemistry. 2015. Vol. 11. P. 1475–1485.
  30. Nagaradja E., Bentabed-Ababsa G., Scalabrini M., Chevallier F., Philippot S., Fontanay S., Duval R.E, Halauko Y.S., Ivashkevich O.A., Matulis V.E., Roisnel T., Mongin F. Deprotometalation–Iodolysis and Computed CH Acidity of 1,2,3- and 1,2,4-Triazoles. Application to the Synthesis of Resveratrol Analogues // Bioorganic & Medicinal Chemistry. 2015. Vol. 23. P. 6355–6363.
  31. Lach J., Jeremies A., Breite D., Abel B., Mahns B., Knupfer M., Matulis V., Ivashkevich O.A., Kersting B. Encapsulation of the 4-Mercaptobenzoate Ligand by Macrocyclic Metal Complexes: Conversion of a Metallocavitand to a Metalloligand // Inorganic Chemistry. 2014. Vol. 53. P. 10825–10834.
  32. Marquise N., Bretel G., Lassagne F., Chevallier F., Roisnel T., Dorcet V.; Halauko Y.S., Ivashkevich O.A., Matulis V. E., Gros P.C., Mongin F. Deproto-metallation Using Mixed Lithium-Zinc and Lithium-Copper Bases and Computed CH Acidity of 2-Substituted Quinolones // RSC Advances. 2014. Vol. 4. P. 19602–19612.
  33. Nagaradja E, Chevallier F., Roisnel T., Dorcet V.; Halauko Y.S., Ivashkevich O.A.; Matulis V. E., Mongin F. Deproto-metallation Using a Mixed Lithium-Zinc Base and Computed CH Acidity of 1-Aryl 1H-Benzotriazoles and 1-Aryl 1H-Indazoles // Organic & Biomolecular Chemistry. 2014. Vol. 10. P. 4878-4885.
  34. Mosalkova A.P., Voitekhovich S.V., Lyakhov A.S., Ivashkevich L.S., Lach J., Kersting B., Gaponik P.N., Ivashkevich O.A. 2-tert-Butyl-5-(2-pyridyl)-2H-tetrazole as chelating ligand in direct synthesis of novel Cu(II) and heterobimetallic Cu(II)/Mn(II) complexes // Dalton Transactions. 2013. Vol. 42. Р. 2985–2997.
  35. Lach J., Mosalkova A.P., Voitekhovich S.V., Gaponik P.N., Kersting B. Tetranuclear complexes composed of dinickel(II) macrocyclic fragments bridged by 5,5’-(1,3-phenylene)bis-1H-tetrazolato and N,N-bis(tetrazol-5-ato)amine coligands: synthesis, structures and magnetic properties // Polyhedron. 2013. Vol. 49. Р. 183–189.
  36. Serebryanskaya T.V., Yung T., Bogdanov A.A., Shchebet A., Johnsen S.A., Lyakhov A.S., Ivashkevich L.S., Ibrahimava Z.A., Garbuzenco T.S., Kolesnikova T.S., Melnova N.I., Gaponik P.N., Ivashkevich O.A. Synthesis, characterization, and biological evaluation of new tetrazole-based platinum(II) and palladium(II) chlorido complexes — Potent cisplatin analogues and their trans isomers // Journal of Inorganic Biochemistry. 2013. Vol. 120. P. 44–53.
  37. Kadiyala R.R., Tilly D., Nagaradja E., Roisnel T., Matulis V.E., Ivashkevich O.A., Halauko Y.S., Chevallier F., Gros P.C., Mongin F. Computed CH Acidity of Biaryl Compoundsand Their Deprotonative Metalation by Using a Mixed Lithium/Zinc-TMP Base // Chemistry- a European Journal. 2013. Vol. 19. P. 7944–7960.
  38. Filippova J.V., Sukhanova A.G., Voitekhovich S.V., Matulis V.E., Sukhanov G.T., Grigoriev Y.V., Ivashkevich O.A. Acid Catalyzed tert-Butylation and Tritylation of 4-Nitro-1,2,3-triazole. Selective Synthesis of 1-Methyl-5-nitro-1,2,3-triazole via 1-tert-Butyl-4-nitro-1,2,3-triazole // Journal of Heterocyclic Chemistry. 2012. Vol. 45. Р. 965–968.
  39. Voitekhovich S.V., Lyakhov A.S., Ivashkevich L.S., Matulis V.E., Grigoriev Y.V., Gaponik P.N., Ivashkevich O.A. Regioselective alkylation of amino- and mercapto-1,2,4-triazoles with t-BuOH-HClO4 // Tetrahedron. 2012. Vol. 68. Р. 4962–4966.
  40. Mazheika A.S., Bredow T., Ivashkevich O.A.,Matulis V.E. Theoretical Study of NO Conversion on Ag/TiO2 Systems. I. Anatase (100) Surface // Journal of Physical Chemistry C, 2012.  Vol. 116. P. 25262–25273.
  41. Ivashkevich L.S., Lyakhov A.S., Serebryanskaya T.V., Gaponik P.N., Ivashkevich O.A. An X-ray powder study of the structure and microstructure of trans-dichloridobis(1,5-diamino-1H-tetrazole-kN4)palladium(II) // Zeitschrift für Kristallographie. 2012. Vol. 227. P. 702–709.
  42. Chevallier F., Blin T., Nagaradja E., Lassagne F., Roisnel T., Halauko Y.S., Matulis V.E., Ivashkevich O.A., Mongin F. Deproto-metallation and computed CH acidity of 2-aryl-1,2,3-triazoles // Organic & Biomolecular Chemistry. 2012. Vol. 10.  P. 4878-4885.
  43. Mazheika A.S., Bredow T., Ivashkevich O.A., Matulis V.E. Theoretical Study of NO Conversion on Ag/TiO2 Systems. II. Rutile (110) Surface // Journal of Physical Chemistry C, 2012. Vol. 116. P. 25274–25285.
  44. Mosalkova A.P., Voitekhovich S.V., Lyakhov A.S.,  Ivashkevich L.S., Gaponik P.N., Ivashkevich O.A. Direct synthesis and characterization of a new copper(II) and zinc(II) 5-R-tetrazolato complexes [R = Me, Ph, 4-Py] with Ethylenediamine and DMSO as Coligands // Zeitschrift für Anorganische und Allgemeine Chemie. 2012. Vol. 638. Р. 103–110.
  45. Nichick M.N., Voitekhovich S.V., Lesnyak V., Matulis Vitaly.E., Zheldakova R.A., Lesnikovich A.I., Ivashkevich O.A. 1-Substituted tetrazole-5-thiol-capped noble metal nanoparticles // Journal of Physical Chemistry C. 2011. Vol. 115. Р. 16928–16933.
  46. Matulis V.E., Palagin D.M., Mazheika A.S., Ivashkevich O.A. Theoretical Study of NO Adsorption on Neutral, Anionic and Cationic Ag8 Clusters // Computational and Theoretical Chemistry. 2011. Vol. 963. P. 422–426.
  47. Mazheika A.S., Bredow T., Matulis V.E., Ivashkevich O.A. Theoretical Study of Adsorption of Ag Clusters on the Anatase TiO2 (100) Surface // Journal of Physical Chemistry C. 2011. Vol. 115. P. 17368–17377.
  48. Voitekhovich S.V., Syre R., Lach J., Matulis V.E., Gaponik P.N., Ivashkevich O.A., Kersting B. A Novel N(3),N(4)-bridging coordination mode of 1-R-Tetrazole-5-thiolates – synthesis, X-ray diffraction, magnetic properties and quantum-chemical study of a macrocyclic dinickel complex coligated by 1-methyltetrazole-5-thiolate // European Journal of Inorganic Chemistry. 2010. Р. 5387–5393.
  49. Serebryanskaya T.V., Matulis V.E., Lyakhov A.S.,  Voitekhovich S.V., Gaponik P.N., Ivashkevich O.A. N-Substituted bis(tetrazol-5-yl)diazenes: synthesis, spectra, X-ray molecular and crystal structures, and quantum-сhemical DFT calculations // Heteroatom Chemistry. 2010. Vol. 21.Р. 24–35.
  50. Mazheika A.S., Matulis V.E., Ivashkevich O.A. Density Functional Study of Adsorption of Agn (n = 2, 4, 8) on Partially Reduced TiO2(110) Surface // Journal of Molecular Structure (Theochem). 2010. Vol. 950. P. 46–52.
  51. Rath S., Nozaki S., Palagin D., Matulis V.E., Ivashkevich O.А., Maki S., Nath Sahu S. Aqueous-Based Synthesis of Atomic Gold Clusters: Geometry and Optical properties // Applied Physics Letters. 2010. Vol. 97. 053103.
  52. Mazheika A.S., Matulis V.E., Ivashkevich O.A. Quantum chemical study of adsorption of Ag2, Ag4 and Ag8 on stoichiometric TiO2(110) surface // Journal of Molecular Structure (Theochem). 2010. Vol. 942. P. 47–54.