Василенко Ирина Владимировна

EN | RU

Главный научный сотрудник
Кандидат химических наук
Доцент

Подразделение: Лаборатория катализа полимеризационных процессов
e-mail: vasilenkoi@bsu.by
Р./тел.: +375 (17) 209-51-75

h-index (Scopus) – 21,
h-index (Web of Science) – 19,
h-index (РИНЦ) – 19,
h-index (Google scholar) – 22
https://scholar.google.com/citations?user=NSfS8igAAAAJ&hl=en
 
Образование
1998–2003 – обучение на химическом факультете Белорусского государственного университета;
2003–2004 – обучение в магистратуре Белорусского государственного университета, защищена магистерская диссертация на тему «Исследование полимеризации гексена-1 на модифицированных классических и нанесенных катализаторах Циглера-Натта»;
2004–2007 – обучение в аспирантуре Белорусского государственного университета; в декабре 2007 защищена кандидатская диссертация на тему «Полимеризация гексена-1 и его сополимеризация со стиролом на гетерогенных и гомогенных катализаторах Циглера-Натта».
 
Продвижение по службе
2007–2008 – младший научный сотрудник лаборатории химической физики и модификации целлюлозы НИИ физико-химических проблем Белорусского государственного университета;
2008–2010 –  научный сотрудник лаборатории катализа полимеризационных процессов НИИ физико-химических проблем Белорусского государственного университета;
2010–2014 – старший научный сотрудник лаборатории катализа полимеризационных процессов НИИ физико-химических проблем Белорусского государственного университета;
с 2014: в.н.с. лаборатории катализа полимеризационных процессов НИИ физико-химических проблем Белорусского государственного университета.
 
Научные интересы, разработки
Катионная полимеризация изобутилена в присутствии модифицированных классических кислот Льюиса и ионных жидкостей, анионная полимеризация раскрытием цикла D,L-лактида, ε-капролактона и ε-капролактама, стереоспецифическая полимеризация стирола и высших a-олефинов.
 

Избранные публикации:

  1. Timofeev G.V., Hulnik M.I., Vasilenko I.V., Ganachaud F., Jacob G., Kostjuk S.V. Chlorinated Solvent-Free Living/Controlled Cationic Ring-Opening Polymerization of Epichlorohydrin Using BF3•OEt2 as Co-initiator: Towards Perfectly Functionalized Polyepichlorohydrin Diols // ACS Appl. Polym. Mater. 2023, 5, 8, 6549-6561. https://doi.org/10.1021/acsapm.3c01105  
  2. Belousov G.K., Vaitusionak A.A., Vasilenko I.V., Ghasemi M., Andruleviciene V., Ivanchenko A., Volyniuk D., Kim H., Grazulevicius J.V., Kostjuk S.V. Through-Space Charge-Transfer Thermally Activated Delayed Fluorescence Alternating Donor Acceptor Copolymers for Non-Doped Solution-Processable OLEDs // Macromolecules, 2023, 56, 2686-2699. https://doi.org/10.1021/acs.macromol.2c02582  
  3. Piskun Y.A., Ksendzov E.A., Resko A.V., Soldatov M.A., Timashev P., Liu H., Vasilenko I.V., Kostjuk S.V. Phosphazene functionalized silsesquioxane-based porous polymer as thermally stable and reusable catalyst for bulk ring-opening polymerization of ε-caprolactone // Polymers, 2023, 15, 1291. https://doi.org/10.3390/polym15051291  
  4. Zaitsev K.V., Trubachev A.D., Oprunenko Y.F., Piskun Yu.A., Vasilenko I.V., Churakov A.V., Kostjuk S.V. Aluminum Salen Complexes Modified with Unsaturated Alcohol: Synthesis, Characterization, and Their Activity Towards Ring-Opening Polymerization of ε-Caprolactone and D,L-Lactide // Molecules, 2023, 28, 1262. https://doi.org/10.3390/molecules28031262
  5. Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Silica gel supported ionic liquids as effective and reusable catalysts for the synthesis of highly reactive polyisobutylene in non-polar media // Polymer Chemistry. 2022, 13. 6625-6636. https://doi.org/10.1039/D2PY01104B
  6. Bohdan M., Shiman D.I., Nikishau P.A., Vasilenko I.V., Kostjuk S.V. Quasiliving carbocationic polymerization of isobutylene using FeCl3 as an efficient and water-tolerant Lewis acid: synthesis of well-defined telechelic polyisobutylenes // Polymer Chemistry. 2022, 13. 6010-6021. https://doi.org/10.1039/D2PY01106A
  7. Hulnik M.I., Kuharenko O.V., Timashev P., Vasilenko I.V., Kostjuk S.V. AlCl3 × OPh2-Co-initiated cationic polymerization of anethole: Facile access to high molecular weight polymers under mild conditions // European Polymer Journal. 2022, 165. № 110983. DOI: 10.1016/j.eurpolymj.2021.110983
  8. Vasilenko I.V., Kostjuk S.V. Homogeneous and heterogeneous catalysts for the synthesis of highly reactive polyisobutylene: discovery, development and perspectives // J. Macromol. Sci.:, Part A: Pure Appl. Chem., 2021, 58, 725-735.   https://doi.org/10.1080/10601325.2021.1956332 
  9. Hulnik M.I., Kuharenko O.V., Vasilenko I.V., Timashev P., Kostjuk S.V. Controlled cationic polymerization of anethole: Accessing high-performance plastic from biomass-derived monomer // ACS Sustainable Chem. Eng., 2021, 9, 6841-6854. https://doi.org/10.1021/acssuschemeng.1c01504
  10. Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Liquid coordination complexes as a new class of catalysts for the synthesis of highly reactive polyisobutylene // Polymer, 2021, 226, 123825. https://doi.org/10.1016/j.polymer.2021.123825
  11. Vaitusionak A.A., Vasilenko I.V., Sych G., Kashina A.V., Simokaitiene J., Grazulevicius J.V., Kostjuk S.V. Atom-transfer radical homo- and copolymerization of carbazole-substituted styrene and perfluorostyrene // Eur. Polym. J.  2020. Vol. 134. P. 109843. (IF=3.862)
  12. Shiman  D. I.,Vasilenko I. V., Kostjuk S. V. Alkoxy Aluminum Chlorides in the Cationic Polymerization of Isobutylene: Co-Initiator, Carbocation Stabilizer and Chain-Transfer Agent // Polym. Chem.  2019.  № 10. P.  5998–6002.  (IF=4.760)
  13. Berezianko I. A., Vasilenko I. V., Kostjuk S. V. Cationic Polymerization of Isobutylene Co-Initiated by Chloroferrate Imidazole-Based Ionic Liquid: Effect of Initiator and Aromatic Compounds // Eur. Polym. J. 2019. № 121 P. 109307. (IF=3.621)
  14. Shiman D. I., Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene and C4 Mixed Feed Using Complexes of Lewis Acids with Ethers: a Comparative Study // Chinese J. Polym. Sci. 2019. Vol.  37. P. 891–897. (IF=2.804)
  15. Vaitusionak A.A.,  Vasilenko I.V.,  Jatautiene E,  Simokaitiene J, Tomkeviciene A.,  Ostrauskaite J., Grazulevicius J.V., Kostjuk S.V.Organocatalytic Controlled Anionic Ring-Opening Polymerization of Carbazole-Containing Thiiranes // Eur. Polym. J. 2019. Vol. 117. P. 179–187. (IF=3.621)
  16. Shiman  D.I., Sayevich  V., Meerbach C.,  Nikishau P.A., Vasilenko I.V., Gaponik N., Kostjuk S.V., Lesnyak V. Robust Polymer Matrix Based on Isobutylene (Co)Polymers for Efficient Encapsulation of Colloidal Semiconductor Nanocrystals // ACS Appl. Nano Mater. 2019.  № 2. P. 956–963.
  17. Hulnik M. I., Vasilenko I. V., Radchenko A. V., Peruch F., Ganachaud F. Kostjuk S. V. Aqueous cationic homo- and co-polymerizations of b-myrcene and styrene: a green route toward terpene-based sustainable elastomers // Polym. Chem. 2018. № 9. P. 5690–5700 (IF=4.927).
  18. Berezianko I.A., Vasilenko I.V., Kostjuk S.V.Acidic Imidazole-Based Ionic Liquids in the Presence of Diisopropyl Ether as Catalysts for the Synthesis of Highly Reactive Polyisobutylene: Effect of Ionic Liquid Nature, Catalyst Aging, and Sonication // Polymer.  2018.  Vol. 145.  P. 382–390. (IF=3.483).
  19. PiskunYu. A., VasilenkoI.V., ZaitsevK.V., OprunenkoYu.F., KostjukS.V. Synthesis of Functional Poly(ε-caprolactone)s via Living Ring-Opening Polymerization of ε-Caprolactone using Functionalized Aluminum Alkoxides as Initiators// Macromol. Chem. Phys., 2017, Vol.218, P.1600580.
  20. Vasilenko I.V., Nikishev P.A., Shiman D.I., Kostjuk S.V. Cationic Polymerization of Isobutylene in Toluene: Toward Well-Defined exo-Olefin Terminated Medium Molecular Weight Polyisobutylenes under Mild Conditions. // Polym. Chem., 2017, Vol.8. P.1417 –1425.
  21. Vasilenko I.V., Berezianko I.A., Shiman D.I., Kostjuk S.V. New Catalyst for the Synthesis of Highly Reactive Polyisobutylene: Chloroaluminate Imidazole-Based Ionic Liquid in the Presence of Diisopropyl Ether // Polym. Chem., 2016, Vol.7. P.5615–5619.
  22. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene Catalyzed by iBuAlCl2 in the Presence of Ethers: Effect of Catalyst Pre-Activation and Mixture of Two Ethers // Polymer. 2016. Vol.99. P.633–641
  23. Vasilenko I.V., Ganachaud F., Kostjuk S.V. New Insights in the Cationic Polymerization in Emulsion Catalyzed by Water-Dispersible Lewis Acid Surfactant Complexes: A Case Study with p-Methoxystyrene// Macromolecules, 2016. Vol. 49. P.3264–3273.
  24. Vasilenko I.V., Yeong H.Y., Delgado M., Ouardad S., Peruch F., Voit B., Ganachaud F., Kostjuk S.V. A catalyst platform for unique cationic (co)polymerization in aqueous emulsion // Angew. Chem. Int. Ed., 2015. Vol.54, P.12728–12723.
  25. Kostjuk S.V., Vasilenko I.V., Shiman D.I.,  Frolov A.N., Gaponik L.V. Highly Reactive Polyisobutylenes via Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-polar Media: Scope and Limitations // Macromol. Symp., 2015. Vol.349. P.94–103.
  26. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene by Complexes of Alkylaluminum Dichlorides with Diisopropyl Ether: An Activating Effect of Water // J. Polym. Sci. Part A: Polym. Chem., 2014. Vol. 52, 2386–2393.
  27. Vasilenko I.V., Shiman, D.I., Kostjuk S.V. Alkylaluminum dichloride–ether complexes which are fully soluble in hydrocarbons as catalysts for the synthesis of exo-olefin terminated polyisobutylene at room temperature // Polym. Chem., 2014, Vol. 5, P.3855–3866.
  28. Zaitsev K.V., Piskun Yu.A., Oprunenko Y.F., Karlov S.S., Zaitseva G.S., Vasilenko I.V., Churakov,A.V., Kostjuk S.V. Controlled Ring-Opening Homo- and Copolymerization of e-Caprolactone and D,L-Lactide by Iminophenolate Aluminum Complexes: An Efficient Approach Towards Well-Defined Macromonomers // J. Polym. Sci. Part A: Polym. Chem., 2014. Vol. 52. P. 1237–1250.
  29. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-Polar Solvents: Effect of Ether Structure on the Selectivity of b-H Elimination // Polymer. 2013. Vol. 54. P. 2235–2242.
  30. Vasilenko I.V., Shiman D.I., Kostjuk S.V. Highly Reactive Polyisobutylenes via AlCl3OBu2-Coinitiated Cationic Polymerization of Isobutylene: Effect of Solvent Polarity, Temperature, and Initiator // J. Polym. Sci. Part A: Polym. Chem. 2012. Vol. 50. P. 750–758.
  31. Piskun Yu.A., Vasilenko I.V., Gaponik L.V., Kostjuk S.V. Activated Anionic Ring-opening Polymerization of ε-Caprolactam with Magnesium Di(ε-caprolactamate) as Initiator: Effect of Magnesium Halides // Polym. Bull. 2012, Vol. 68. P. 1501–1513.
  32. Kostjuk S.V., Ganachaud F., Radchenko A.V., Vasilenko I.V. Cationic Polymerization of Styrene Derivatives and Cyclopentadiene Catalyzed by B(C6F5)3 in Aqueous Media: Comparison of Suspension, Emulsion and Dispersion Processes //  Macromol. Symp. 2011. Vol. 308. P. 1–7.
  33. Kukhta N.A., Vasilenko I.V., Kostjuk S.V. Room Temperature Cationic Polymerization of b-Pinene using Modified AlCl3 Catalyst: Toward Sustainable Plastics from Renewable Biomass Resources // Green Chem. 2011. Vol.13. P. 2362-2364.
  34. Frolov, A.N.; Kostjuk, S.V.; Vasilenko, I.V.; Kaputsky, F.N. Controlled Cationic Polymerization of Styrene Using AlCl3OBu2 as a Co-initiator: Towards High Molecular Weight Polystyrenes at Elevated Temperatures // J. Polym. Sci. Part A: Polym. Chem. 2010. Vol. 48. P.3736-3743.
  35. Vasilenko I.V., Frolov A.N., Kostjuk, S.V. Cationic Polymerization of Isobutylene Using AlCl3OBu2 as a Co-initiator: Synthesis of Highly Reactive Polyisobutylene //  Macromolecules. 2010. Vol. 43. P. 5503-5507.
  36. Piskun Yu.A., Vasilenko I.V., Kostjuk S.V., Zaitsev K.V., Zaitseva G.S.; Karlov S.S. Titanium Complexes of Dialkanolamine Ligands as Initiators for Living Ring-Opening Polymerization of ε-Caprolactone //  J. Polym. Sci. Part A: Polym. Chem. 2010, Vol. 48. P. 1230-1240.

Патенты
  1. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I. Process for preparing high-reactivity isobutene homo- or copolymers., RU Patent 2555400
  2. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,637,619
  3. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,349,977
  4. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers. EP2536768.
  5. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers.WO2011101281.