h-index (Scopus) – 21,
h-index (Web of Science) – 19,
h-index (РИНЦ) – 19,
h-index (Google scholar) – 22
https://scholar.google.com/citations?user=NSfS8igAAAAJ&hl=en
Образование
1998–2003 – обучение на химическом факультете Белорусского государственного университета;
2003–2004 – обучение в магистратуре Белорусского государственного университета, защищена магистерская диссертация на тему «Исследование полимеризации гексена-1 на модифицированных классических и нанесенных катализаторах Циглера-Натта»;
2004–2007 – обучение в аспирантуре Белорусского государственного университета; в декабре 2007 защищена кандидатская диссертация на тему «Полимеризация гексена-1 и его сополимеризация со стиролом на гетерогенных и гомогенных катализаторах Циглера-Натта».
Продвижение по службе
2007–2008 – младший научный сотрудник лаборатории химической физики и модификации целлюлозы НИИ физико-химических проблем Белорусского государственного университета;
2008–2010 – научный сотрудник лаборатории катализа полимеризационных процессов НИИ физико-химических проблем Белорусского государственного университета;
2010–2014 – старший научный сотрудник лаборатории катализа полимеризационных процессов НИИ физико-химических проблем Белорусского государственного университета;
с 2014: в.н.с. лаборатории катализа полимеризационных процессов НИИ физико-химических проблем Белорусского государственного университета.
Научные интересы, разработки
Катионная полимеризация изобутилена в присутствии модифицированных классических кислот Льюиса и ионных жидкостей, анионная полимеризация раскрытием цикла D,L-лактида, ε-капролактона и ε-капролактама, стереоспецифическая полимеризация стирола и высших a-олефинов.
Избранные публикации:
- Timofeev G.V., Hulnik M.I., Vasilenko I.V., Ganachaud F., Jacob G., Kostjuk S.V. Chlorinated Solvent-Free Living/Controlled Cationic Ring-Opening Polymerization of Epichlorohydrin Using BF3•OEt2 as Co-initiator: Towards Perfectly Functionalized Polyepichlorohydrin Diols // ACS Appl. Polym. Mater. 2023, 5, 8, 6549-6561. https://doi.org/10.1021/acsapm.3c01105
- Belousov G.K., Vaitusionak A.A., Vasilenko I.V., Ghasemi M., Andruleviciene V., Ivanchenko A., Volyniuk D., Kim H., Grazulevicius J.V., Kostjuk S.V. Through-Space Charge-Transfer Thermally Activated Delayed Fluorescence Alternating Donor Acceptor Copolymers for Non-Doped Solution-Processable OLEDs // Macromolecules, 2023, 56, 2686-2699. https://doi.org/10.1021/acs.macromol.2c02582
- Piskun Y.A., Ksendzov E.A., Resko A.V., Soldatov M.A., Timashev P., Liu H., Vasilenko I.V., Kostjuk S.V. Phosphazene functionalized silsesquioxane-based porous polymer as thermally stable and reusable catalyst for bulk ring-opening polymerization of ε-caprolactone // Polymers, 2023, 15, 1291. https://doi.org/10.3390/polym15051291
- Zaitsev K.V., Trubachev A.D., Oprunenko Y.F., Piskun Yu.A., Vasilenko I.V., Churakov A.V., Kostjuk S.V. Aluminum Salen Complexes Modified with Unsaturated Alcohol: Synthesis, Characterization, and Their Activity Towards Ring-Opening Polymerization of ε-Caprolactone and D,L-Lactide // Molecules, 2023, 28, 1262. https://doi.org/10.3390/molecules28031262
- Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Silica gel supported ionic liquids as effective and reusable catalysts for the synthesis of highly reactive polyisobutylene in non-polar media // Polymer Chemistry. 2022, 13. 6625-6636. https://doi.org/10.1039/D2PY01104B
- Bohdan M., Shiman D.I., Nikishau P.A., Vasilenko I.V., Kostjuk S.V. Quasiliving carbocationic polymerization of isobutylene using FeCl3 as an efficient and water-tolerant Lewis acid: synthesis of well-defined telechelic polyisobutylenes // Polymer Chemistry. 2022, 13. 6010-6021. https://doi.org/10.1039/D2PY01106A
- Hulnik M.I., Kuharenko O.V., Timashev P., Vasilenko I.V., Kostjuk S.V. AlCl3 × OPh2-Co-initiated cationic polymerization of anethole: Facile access to high molecular weight polymers under mild conditions // European Polymer Journal. 2022, 165. № 110983. DOI: 10.1016/j.eurpolymj.2021.110983
- Vasilenko I.V., Kostjuk S.V. Homogeneous and heterogeneous catalysts for the synthesis of highly reactive polyisobutylene: discovery, development and perspectives // J. Macromol. Sci.:, Part A: Pure Appl. Chem., 2021, 58, 725-735. https://doi.org/10.1080/10601325.2021.1956332
- Hulnik M.I., Kuharenko O.V., Vasilenko I.V., Timashev P., Kostjuk S.V. Controlled cationic polymerization of anethole: Accessing high-performance plastic from biomass-derived monomer // ACS Sustainable Chem. Eng., 2021, 9, 6841-6854. https://doi.org/10.1021/acssuschemeng.1c01504
- Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Liquid coordination complexes as a new class of catalysts for the synthesis of highly reactive polyisobutylene // Polymer, 2021, 226, 123825. https://doi.org/10.1016/j.polymer.2021.123825
- Vaitusionak A.A., Vasilenko I.V., Sych G., Kashina A.V., Simokaitiene J., Grazulevicius J.V., Kostjuk S.V. Atom-transfer radical homo- and copolymerization of carbazole-substituted styrene and perfluorostyrene // Eur. Polym. J. 2020. Vol. 134. P. 109843. (IF=3.862)
- Shiman D. I.,Vasilenko I. V., Kostjuk S. V. Alkoxy Aluminum Chlorides in the Cationic Polymerization of Isobutylene: Co-Initiator, Carbocation Stabilizer and Chain-Transfer Agent // Polym. Chem. 2019. № 10. P. 5998–6002. (IF=4.760)
- Berezianko I. A., Vasilenko I. V., Kostjuk S. V. Cationic Polymerization of Isobutylene Co-Initiated by Chloroferrate Imidazole-Based Ionic Liquid: Effect of Initiator and Aromatic Compounds // Eur. Polym. J. 2019. № 121 P. 109307. (IF=3.621)
- Shiman D. I., Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene and C4 Mixed Feed Using Complexes of Lewis Acids with Ethers: a Comparative Study // Chinese J. Polym. Sci. 2019. Vol. 37. P. 891–897. (IF=2.804)
- Vaitusionak A.A., Vasilenko I.V., Jatautiene E, Simokaitiene J, Tomkeviciene A., Ostrauskaite J., Grazulevicius J.V., Kostjuk S.V.Organocatalytic Controlled Anionic Ring-Opening Polymerization of Carbazole-Containing Thiiranes // Eur. Polym. J. 2019. Vol. 117. P. 179–187. (IF=3.621)
- Shiman D.I., Sayevich V., Meerbach C., Nikishau P.A., Vasilenko I.V., Gaponik N., Kostjuk S.V., Lesnyak V. Robust Polymer Matrix Based on Isobutylene (Co)Polymers for Efficient Encapsulation of Colloidal Semiconductor Nanocrystals // ACS Appl. Nano Mater. 2019. № 2. P. 956–963.
- Hulnik M. I., Vasilenko I. V., Radchenko A. V., Peruch F., Ganachaud F. Kostjuk S. V. Aqueous cationic homo- and co-polymerizations of b-myrcene and styrene: a green route toward terpene-based sustainable elastomers // Polym. Chem. 2018. № 9. P. 5690–5700 (IF=4.927).
- Berezianko I.A., Vasilenko I.V., Kostjuk S.V.Acidic Imidazole-Based Ionic Liquids in the Presence of Diisopropyl Ether as Catalysts for the Synthesis of Highly Reactive Polyisobutylene: Effect of Ionic Liquid Nature, Catalyst Aging, and Sonication // Polymer. 2018. Vol. 145. P. 382–390. (IF=3.483).
- PiskunYu. A., VasilenkoI.V., ZaitsevK.V., OprunenkoYu.F., KostjukS.V. Synthesis of Functional Poly(ε-caprolactone)s via Living Ring-Opening Polymerization of ε-Caprolactone using Functionalized Aluminum Alkoxides as Initiators// Macromol. Chem. Phys., 2017, Vol.218, P.1600580.
- Vasilenko I.V., Nikishev P.A., Shiman D.I., Kostjuk S.V. Cationic Polymerization of Isobutylene in Toluene: Toward Well-Defined exo-Olefin Terminated Medium Molecular Weight Polyisobutylenes under Mild Conditions. // Polym. Chem., 2017, Vol.8. P.1417 –1425.
- Vasilenko I.V., Berezianko I.A., Shiman D.I., Kostjuk S.V. New Catalyst for the Synthesis of Highly Reactive Polyisobutylene: Chloroaluminate Imidazole-Based Ionic Liquid in the Presence of Diisopropyl Ether // Polym. Chem., 2016, Vol.7. P.5615–5619.
- Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene Catalyzed by iBuAlCl2 in the Presence of Ethers: Effect of Catalyst Pre-Activation and Mixture of Two Ethers // Polymer. 2016. Vol.99. P.633–641
- Vasilenko I.V., Ganachaud F., Kostjuk S.V. New Insights in the Cationic Polymerization in Emulsion Catalyzed by Water-Dispersible Lewis Acid Surfactant Complexes: A Case Study with p-Methoxystyrene// Macromolecules, 2016. Vol. 49. P.3264–3273.
- Vasilenko I.V., Yeong H.Y., Delgado M., Ouardad S., Peruch F., Voit B., Ganachaud F., Kostjuk S.V. A catalyst platform for unique cationic (co)polymerization in aqueous emulsion // Angew. Chem. Int. Ed., 2015. Vol.54, P.12728–12723.
- Kostjuk S.V., Vasilenko I.V., Shiman D.I., Frolov A.N., Gaponik L.V. Highly Reactive Polyisobutylenes via Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-polar Media: Scope and Limitations // Macromol. Symp., 2015. Vol.349. P.94–103.
- Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene by Complexes of Alkylaluminum Dichlorides with Diisopropyl Ether: An Activating Effect of Water // J. Polym. Sci. Part A: Polym. Chem., 2014. Vol. 52, 2386–2393.
- Vasilenko I.V., Shiman, D.I., Kostjuk S.V. Alkylaluminum dichloride–ether complexes which are fully soluble in hydrocarbons as catalysts for the synthesis of exo-olefin terminated polyisobutylene at room temperature // Polym. Chem., 2014, Vol. 5, P.3855–3866.
- Zaitsev K.V., Piskun Yu.A., Oprunenko Y.F., Karlov S.S., Zaitseva G.S., Vasilenko I.V., Churakov,A.V., Kostjuk S.V. Controlled Ring-Opening Homo- and Copolymerization of e-Caprolactone and D,L-Lactide by Iminophenolate Aluminum Complexes: An Efficient Approach Towards Well-Defined Macromonomers // J. Polym. Sci. Part A: Polym. Chem., 2014. Vol. 52. P. 1237–1250.
- Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-Polar Solvents: Effect of Ether Structure on the Selectivity of b-H Elimination // Polymer. 2013. Vol. 54. P. 2235–2242.
- Vasilenko I.V., Shiman D.I., Kostjuk S.V. Highly Reactive Polyisobutylenes via AlCl3OBu2-Coinitiated Cationic Polymerization of Isobutylene: Effect of Solvent Polarity, Temperature, and Initiator // J. Polym. Sci. Part A: Polym. Chem. 2012. Vol. 50. P. 750–758.
- Piskun Yu.A., Vasilenko I.V., Gaponik L.V., Kostjuk S.V. Activated Anionic Ring-opening Polymerization of ε-Caprolactam with Magnesium Di(ε-caprolactamate) as Initiator: Effect of Magnesium Halides // Polym. Bull. 2012, Vol. 68. P. 1501–1513.
- Kostjuk S.V., Ganachaud F., Radchenko A.V., Vasilenko I.V. Cationic Polymerization of Styrene Derivatives and Cyclopentadiene Catalyzed by B(C6F5)3 in Aqueous Media: Comparison of Suspension, Emulsion and Dispersion Processes // Macromol. Symp. 2011. Vol. 308. P. 1–7.
- Kukhta N.A., Vasilenko I.V., Kostjuk S.V. Room Temperature Cationic Polymerization of b-Pinene using Modified AlCl3 Catalyst: Toward Sustainable Plastics from Renewable Biomass Resources // Green Chem. 2011. Vol.13. P. 2362-2364.
- Frolov, A.N.; Kostjuk, S.V.; Vasilenko, I.V.; Kaputsky, F.N. Controlled Cationic Polymerization of Styrene Using AlCl3OBu2 as a Co-initiator: Towards High Molecular Weight Polystyrenes at Elevated Temperatures // J. Polym. Sci. Part A: Polym. Chem. 2010. Vol. 48. P.3736-3743.
- Vasilenko I.V., Frolov A.N., Kostjuk, S.V. Cationic Polymerization of Isobutylene Using AlCl3OBu2 as a Co-initiator: Synthesis of Highly Reactive Polyisobutylene // Macromolecules. 2010. Vol. 43. P. 5503-5507.
- Piskun Yu.A., Vasilenko I.V., Kostjuk S.V., Zaitsev K.V., Zaitseva G.S.; Karlov S.S. Titanium Complexes of Dialkanolamine Ligands as Initiators for Living Ring-Opening Polymerization of ε-Caprolactone // J. Polym. Sci. Part A: Polym. Chem. 2010, Vol. 48. P. 1230-1240.
Патенты
- König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I. Process for preparing high-reactivity isobutene homo- or copolymers., RU Patent 2555400
- König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,637,619
- König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,349,977
- König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers. EP2536768.
- König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers.WO2011101281.