НИИ ФХП БГУ

Research Institute for Physical Chemical Problems
of the Belarusian State University

Kostiuk Sergei


Head of the laboratory of catalysis of polymerization processesof the Research Institute for Physical Chemical Problems
of the Belarusian State University

 
PhD, Associate professor
 
h-index (Scopus) –  17,
h-index (Web of Science) –  17,
h-index (РИНЦ) –  12,
h-index (Google science) – 20,
(https://scholar.google.com/citations?user=x6rmcYEAAAAJ&hl=en )
 
Education: 

1994-1999:  Diploma in Chemistry at Chemistry Department, Belarusian State University, June 25, 1999. Thesis title: “Living” cationic polymerization of styrene. Average mark 4.90 in 0...5 scale. Diploma A № 0013890.
1999-2002 – Ph.D. thesis at theInstitute of Physical and Organic Chemistry of the National Academy of Sciences of the Republic of Belarus. Thesis title: “Living” cationic polymerization of styrene in the presence of electron donors. Ph.D. degree in Polymer Chemistry, Belarusian State University, December 27, 2002.
 
 
Career:

Since 2008 –Head of the laboratory of catalysis of polymerization processes, Research Institute for Physical Chemical Problems, Belarusian State University.
2005-2008 –Senior Researcher, Research Institute for Physical Chemical Problems, Belarusian State University.
2003-2005 –Researcher, Research Institute for Physical Chemical Problems, Belarusian State University.
2002-2003 –Junior Researcher, Research Institute for Physical Chemical Problems, Belarusian State University.
1999-2002–PhD student, Belarusian State University.
1999 –Junior Researcher, Research Institute for Physical Chemical Problems, Belarusian State University.
 
Current research activity, main achievements:
 
Polymer design and synthesis including controlled cationic polymerization, ring-opening anionic polymerization and metallocene catalysis; cationic polymerization in aqueous media; polymerization kinetics and mechanisms
 
List of the selected publications:
  1. Kuznetsova D., Timashev P., Ageykin A., Koroleva A., Deiwick A., Shpichka A., Solovieva A., Kostjuk S., Meleshina A., Rodimova S., Akovanceva A., Butnaru D., Frolova A., Zagaynova E., Chichkov B., Bagratashvili V., Timashev P. Surface micromorphology of cross-linked tetrafunctional polylactide scaffolds inducing vessel growth and bone formation. // Biofabrication 2017, https://doi.org/10.1088/1758-5090/aa6725.
  2. Piskun Yu. A., Vasilenko I.V., Zaitsev K.V., Oprunenko Yu.F., Kostjuk S.V. Synthesis of Functional Poly(ε-caprolactone)s via Living Ring-Opening Polymerization of ε-Caprolactone using Functionalized Aluminum Alkoxides as Initiators // Macromol. Chem. Phys., 2017, Vol.218, P.1600580.  Vasilenko I.V., Nikishev P.A., Shiman D.I., Kostjuk S.V. Cationic Polymerization of Isobutylene in Toluene: Toward Well-Defined exo-Olefin Terminated Medium Molecular Weight Polyisobutylenes under Mild Conditions. // Polym. Chem., 2017, Vol.8. P.1417 –1425.
  3. RozentsvetV.A.,Kozlov V.G., Sablina N.A., Stotskaya O.A., Peruch F., Kostjuk S.V.A new insight into the polymerization mechanism of 1,3-dienes cationic polymerization. IV. Mechanism of unsaturation loss in the polymerization of isoprene  // Polym. Chem., 2017. Vol. 8. P.926–935.
  4. Simkus G., Tomkeviciene A., Volyniuk D., Kostjuk S.V., Grazulevicius J.V. Synthesis and properties of photocross-linkable carbazole dimers // React. Funct. Polym. 2017. Vol.110. P. 47–54.
  5. Keruckiene R., Volyniuk D., Ostrauskaite J., Peciulyte L., Grazulevicius J.V., Kostjuk S.V., Lazauskas A. Derivatives of 2-phenylindole and carbazole as host materials for phosphorescent organic light emitting diodes // Dyes Pigm. 2017. Vol.137, P.58–68.
  6. Vasilenko I.V., Berezianko I.A., Shiman D.I., Kostjuk S.V. New Catalyst for the Synthesis of Highly Reactive Polyisobutylene: Chloroaluminate Imidazole-Based Ionic Liquid in the Presence of Diisopropyl Ether // Polym. Chem., 2016, Vol.7. P.5615–5619.
  7. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene Catalyzed by iBuAlCl2 in the Presence of Ethers: Effect of Catalyst Pre-Activation and Mixture of Two Ethers // Polymer. 2016. Vol.99. P.633–641.
  8. Rozentsvet V.A., Kozlov V.G., Korovina N.A., Stotskaya O.A., Gnezdilov O.I., Kostjuk S.V. The Structure of Cationic Polyisoprene: Branching versus Cyclization // Macromol. Chem. Phys., 2016. Vol. 217.  P.1860–1867.
  9. Rozentsvet V.A.,Korovina N.A., Stotskaya O.A., Kuznetsova M.G., Peruch F., Kostjuk S.V. Comprehensive Structural Characterization of Polyisoprene Synthesized via Cationic Mechanism // J. Polym. Sci. Part A: Polym. Chem., 2016. Vol. 54. P.2430–2442.
  10. Vasilenko I.V., Ganachaud F., Kostjuk S.V. New Insights in the Cationic Polymerization in Emulsion Catalyzed by Water-Dispersible Lewis Acid Surfactant Complexes: A Case Study with p-Methoxystyrene // Macromolecules, 2016. Vol. 49. P.3264–3273.
  11. Timashev P., Kuznetsova D., Koroleva A., Prodanets N., Deiwick A., Piskun Yu., Bardakova K., Dzhoyashvili N., Kostjuk. S., Zagaynova E., Rochev Y., Chichkov B., Bagratashvili V. Novel biodegradable star-shaped polylactide scaffolds for bone regeneration fabricated by two-photon polymerization // Nanomedicine, 2016.Vol.11. P.1041-1053.
  12. Vasilenko I.V., Yeong H.Y., Delgado M., Ouardad S., Peruch F., Voit B., Ganachaud F., Kostjuk S.V. A catalyst platform for unique cationic (co)polymerization in aqueous emulsion // Angew. Chem. Int. Ed., 2015. Vol.54, P.12728–12723.
  13. Ouardad S., Wirotius A.-L., Kostjuk S.V., Ganachaud F., Peruch F. Carbocationic polymerization of isoprene using cumyl initiators: progress in understanding the side reactions //  RSC Advances, 2015. Vol. 5. P.59218–59225.
  14. Kostjuk S.V.; Vasilenko, I.V.; Shiman, D.I.; Frolov, A.N.; Gaponik, L.V. Highly Reactive Polyisobutylenes via Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-polar Media: Scope and Limitations // Macromol. Symp., 2015. Vol.349. P.94–103.
  15. Kostjuk S.V. Recent progress in the Lewis acids co-initiated cationic polymerization of isobutylene and 1,3-dienes // RSC Advances. 2015. Vol. 5, P.13125–13144.
  16. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene by Complexes of Alkylaluminum Dichlorides with Diisopropyl Ether: An Activating Effect of Water // J. Polym. Sci. Part A: Polym. Chem., 2014. Vol. 52, 2386–2393.
  17. Rozentsvet V.A., Kozlov V.A., Korovina N.A., Novakov I.A., Kostjuk S.V. A New Insight into the Mechanism of 1,3-Dienes Cationic Polymerization. III: Polymerization of 1,3-pentadiene with CF3COOD/TiCl4 initiating system: chain end structure and kinetics // Macromol. Chem. Phys., 2014. Vol.215. P.1239–1249.
  18. Vasilenko I.V., Shiman, D.I., Kostjuk S.V. Alkylaluminum dichloride–ether complexes which are fully soluble in hydrocarbons as catalysts for the synthesis of exo-olefin terminated polyisobutylene at room temperature // Polym. Chem., 2014, Vol.5, P.3855–3866.
  19. Zaitsev K.V., Piskun Yu.A., Oprunenko Y.F., Karlov S.S., Zaitseva G.S., Vasilenko I.V., Churakov,A.V., Kostjuk S.V. Controlled Ring-Opening Homo- and Copolymerization of e-Caprolactone and D,L-Lactide by Iminophenolate Aluminum Complexes: An Efficient Approach Towards Well-Defined Macromonomers // J. Polym. Sci. Part A: Polym. Chem., 2014. Vol. 52. P.1237–1250.
  20. Jadhav A.H., Chinnappan A., Patil R.P., Kostjuk S.V., Kim H. Green chemical conversion of fructose into 5-hydroxymethylfurfural (HMF) using unsymmetrical dicationic ionic liquids under mild reaction condition //  Chemical Engineering Journal. 2014. Vol. 243. P.92–98.
  21. Rozentsvet V.A., KozlovV.G., Korovina N.A., Kostjuk S.V. A New Insight into the Mechanism of 1,3-Dienes Cationic Polymerization. I. Polymerization of 1,3-Pentadiene with tBuCl/TiCl4 Initiating System: Kinetic and Mechanistic Study //  Macromol. Chem. Phys. 2013. Vol.214. P.2694–2704.
  22. Rozentsvet V.A., Korovina N.A., Ivanova V.P., Kuznetsova M.G., Kostjuk, S.V. A New Insight into the Mechanism of 1,3-Dienes Cationic Polymerization. II. Structure of Poly(1,3-pentadiene) Synthesized with tBuCl/TiCl4 Initiating System // J. Polym. Sci. Part A: Polym. Chem. 2013. Vol. 51. P.3297–3307.
  23. Rozentsvet V.A., KozlovV.G., Ziganshina E.F., BoreikoN.P., Kostjuk S.V. Cationic Polymerization of Isoprene using Zinc Halides as Co-initiators: Toward well-defined oligo(isoprene)s under mild conditions // Polym. Int. 2013. Vol.62, P.817–826.
  24. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-Polar Solvents: Effect of Ether Structure on the Selectivity of b-H Elimination // Polymer. 2013. Vol. 54. P.2235–2242.
  25. Radchenko A.V., Kostjuk S.V., Ganachaud F. Cationic Polymerization of Isobutyl Vinyl Ether in Aqueous Media: Physicochemical Tricks to Fight against Thermal Runaway // Polym. Chem. 2013. Vol.4. P.1883–1892.
  26. Rozentsvet V.A., KozlovV.G., Korovina N.A., Ivanova V.P., Kostjuk S.V. Cationic Polymerization of 1,3-Pentadiene Co-initiated by Zinc Halides // J. Appl. Polym. Sci. 2013. Vol.128.  P.1771–1778.
  27. Kostjuk S.V., Yeong H.Y., Voit B. Cationic Polymerization of Isobutylene at Room Temperature // J. Polym. Sci. Part A: Polym. Chem. 2013. Vol.51. P.471–486.
  28. Ouardad S., Bakleh M-E., Kostjuk S.V., Ganachaud F., Puskas J.E., Deffieux A., Peruch F. Bio-inspired Cationic Polymerization of Isoprene and Analogues: the Current Situation // Polym. Int. 2012. Vol.61. P.149–156.
  29. Vasilenko I.V., Shiman D.I., Kostjuk S.V. Highly Reactive Polyisobutylenes via AlCl3OBu2-Coinitiated Cationic Polymerization of Isobutylene: Effect of Solvent Polarity, Temperature, and Initiator // J. Polym. Sci. Part A: Polym. Chem. 2012. Vol. 50. P.750–758.
  30. Piskun Yu.A., Vasilenko I.V., Gaponik L.V., Kostjuk S.V. Activated Anionic Ring-opening Polymerization of ε-Caprolactam with Magnesium Di(ε-caprolactamate) as Initiator: Effect of Magnesium Halides //Polym. Bull. 2012, Vol.68. P.1501–1513.
  31. Kostjuk S.V., Ganachaud F., Radchenko A.V., Vasilenko I.V. Cationic Polymerization of Styrene Derivatives and Cyclopentadiene Catalyzed by B(C6F5)3 in Aqueous Media: Comparison of Suspension, Emulsion and Dispersion Processes //  Macromol. Symp.2011. Vol.308. P.1–7.
  32. Ouardad S., Kostjuk S.V., Ganachaud F., Puskas J.E., Deffieux A., Peruch F. Cationation of Dimethylallyl Alcohols by B(C6F5)3 as Models of the (re)Initiation Reaction in the Bio-inspired Cationic Polymerization of Isoprene // J. Polym. Sci. Part A: Polym. Chem.2011. Vol. 49. P. 4948–4954.
  33. Kukhta N.A., Vasilenko I.V., Kostjuk S.V. Room Temperature Cationic Polymerization of b-Pinene using Modified AlCl3 Catalyst: Toward Sustainable Plastics from Renewable Biomass Resources // Green Chem. 2011. Vol.13. P.2362-2364.
  34. Kostjuk S.V., Ouardad S., Peruch F., Deffieux A., Absalon C., Ganachaud F., Puskas J.E. Carbocationic Polymerization of Isoprene Co-initiated by B(C6F5)3: An Alternative Route Towards Natural Rubber Polymer Analogues?  // Macromolecules. 2011. Vol. 44. P.1372–1384.
  35. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I. Process for preparing high-reactivity isobutene homo- or copolymers., RU Patent 2555400
  36. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,637,619
  37. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,349,977
  38. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers. EP2536768.
  39. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers.WO2011101281.
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