НИИ ФХП БГУ

Research Institute for Physical Chemical Problems
of the Belarusian State University

Vasilenko Irina

Leading researcher in the laboratory of catalysis of polymerization processesof the Research Institute for Physical Chemical Problems
of the Belarusian State University

 
PhD, Associate professor
 
h-index (Scopus) – 12
h-index (Web of Science) – 12
h-index (РИНЦ) – 7
h-index (Google science) – 12
(https://scholar.google.com/citations?user=NSfS8igAAAAJ&hl=en)
 
Education
1998–2003:BSc. degree in Chemistry at Chemical Department, Belarusian State University, June 26, 2003. Thesis title is “The 1-hexene polymerization using TiCl4-Al(C6H13)3×Mg(C6H13)2 catalyst system”.
2003–2004:MSc. degree in Chemistry at Chemical Department, Belarusian State University, September 10, 2004. Thesis title is “Investigation of the 1-hexene polymerization in the presence of modified classical and supported magnesium – titaniumZiegler-Natta catalysts”.
2004–2007:Ph.D. thesis at theInstitute of Physical and Organic Chemistry of the National Academy of Sciences of the Republic of Belarus. Thesis title is “Polymerization of 1-hexene and its copolymerization with styrene in the presence of heterogeneous and homogeneous Zieglar–Natta catalysts”. Ph.D. degree in Polymer Chemistry, Belarusian State University, December 27, 2007.
 
Career
2007–2008:Junior Researcher, Research Institute for Physical Chemical Problems, Belarusian State University.
2008–2010:Researcher, Research Institute for Physical Chemical Problems, Belarusian State University.
2010–2014:Senior Researcher, Research Institute for Physical Chemical Problems, Belarusian State University.
Since 2014:Leading Researcher, Research Institute for Physical Chemical Problems, Belarusian State University.
 
Current research activity, main achievements
Cationic polymerization of isobutylene in the presence of modified Lewis acids and ionic liquid, anionic ring-opening polymerization of D,L-lictide, ε-caprolactone, and ε-caprolactam, stereoselective polymerization of styrene and higher a-olefins.
 
List of the selected publications:
  1. Piskun Yu. A., Vasilenko I.V., Zaitsev K.V., Oprunenko Yu.F., Kostjuk S.V. Synthesis of Functional Poly(ε-caprolactone)s via Living Ring-Opening Polymerization of ε-Caprolactone using Functionalized Aluminum Alkoxides as Initiators// Macromol. Chem. Phys., 2017, Vol.218, P.1600580.
  2. Vasilenko I.V., Nikishev P.A., Shiman D.I., Kostjuk S.V. Cationic Polymerization of Isobutylene in Toluene: Toward Well-Defined exo-Olefin Terminated Medium Molecular Weight Polyisobutylenes under Mild Conditions. // Polym. Chem., 2017, Vol.8. P.1417 –1425.
  3. Vasilenko I.V., Berezianko I.A., Shiman D.I., Kostjuk S.V. New Catalyst for the Synthesis of Highly Reactive Polyisobutylene: Chloroaluminate Imidazole-Based Ionic Liquid in the Presence of Diisopropyl Ether// Polym. Chem., 2016, Vol.7. P.5615–5619.
  4. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene Catalyzed by iBuAlCl2 in the Presence of Ethers: Effect of Catalyst Pre-Activation and Mixture of Two Ethers// Polymer. 2016. Vol.99. P.633–641
  5. Vasilenko I.V., Ganachaud F., Kostjuk S.V. New Insights in the Cationic Polymerization in Emulsion Catalyzed by Water-Dispersible Lewis Acid Surfactant Complexes: A Case Study with p-Methoxystyrene// Macromolecules, 2016. Vol. 49. P.3264–3273.
  6. Vasilenko I.V., Yeong H.Y., Delgado M., Ouardad S., Peruch F., Voit B., Ganachaud F., Kostjuk S.V. A catalyst platform for unique cationic (co)polymerization in aqueous emulsion// Angew. Chem. Int. Ed., 2015. Vol.54, P.12728–12723.
  7. Kostjuk S.V., Vasilenko I.V., Shiman D.I.,  Frolov A.N., Gaponik L.V. Highly Reactive Polyisobutylenes via Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-polar Media: Scope and Limitations// Macromol. Symp., 2015. Vol.349. P.94–103.
  8. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene by Complexes of Alkylaluminum Dichlorides with Diisopropyl Ether: An Activating Effect of Water// J. Polym. Sci. Part A: Polym. Chem., 2014. Vol. 52, 2386–2393.
  9. Vasilenko I.V., Shiman, D.I., Kostjuk S.V. Alkylaluminum dichloride–ether complexes which are fully soluble in hydrocarbons as catalysts for the synthesis of exo-olefin terminated polyisobutylene at room temperature// Polym. Chem., 2014, Vol.5, P.3855–3866.
  10. Zaitsev K.V., Piskun Yu.A., Oprunenko Y.F., Karlov S.S., Zaitseva G.S., Vasilenko I.V., Churakov,A.V., Kostjuk S.V. Controlled Ring-Opening Homo- and Copolymerization of e-Caprolactone and D,L-Lactide by Iminophenolate Aluminum Complexes: An Efficient Approach Towards Well-Defined Macromonomers// J. Polym. Sci. Part A: Polym. Chem., 2014. Vol. 52. P.1237–1250.
  11. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-Polar Solvents: Effect of Ether Structure on the Selectivity of b-H Elimination // Polymer. 2013. Vol. 54. P.2235–2242.
  12. Vasilenko I.V., Shiman D.I., Kostjuk S.V. Highly Reactive Polyisobutylenes via AlCl3OBu2-Coinitiated Cationic Polymerization of Isobutylene: Effect of Solvent Polarity, Temperature, and Initiator// J. Polym. Sci. Part A: Polym. Chem. 2012. Vol. 50. P.750–758.
  13. Piskun Yu.A., Vasilenko I.V., Gaponik L.V., Kostjuk S.V. Activated Anionic Ring-opening Polymerization of ε-Caprolactam with Magnesium Di(ε-caprolactamate) as Initiator: Effect of Magnesium Halides//Polym. Bull. 2012, Vol.68. P.1501–1513.
  14. Kostjuk S.V., Ganachaud F., Radchenko A.V., Vasilenko I.V. Cationic Polymerization of Styrene Derivatives and Cyclopentadiene Catalyzed by B(C6F5)3 in Aqueous Media: Comparison of Suspension, Emulsion and Dispersion Processes//  Macromol. Symp.2011. Vol.308. P.1–7.
  15. Kukhta N.A., Vasilenko I.V., Kostjuk S.V. Room Temperature Cationic Polymerization of b-Pinene using Modified AlCl3 Catalyst: Toward Sustainable Plastics from Renewable Biomass Resources// Green Chem. 2011. Vol.13. P.2362-2364.
  16. Frolov, A.N.; Kostjuk, S.V.; Vasilenko, I.V.; Kaputsky, F.N. Controlled Cationic Polymerization of Styrene Using AlCl3OBu2 as a Co-initiator: Towards High Molecular Weight Polystyrenes at Elevated Temperatures// J. Polym. Sci. Part A: Polym. Chem. 2010. Vol. 48. P.3736-3743.
  17. Vasilenko I.V., Frolov A.N., Kostjuk, S.V. Cationic Polymerization of Isobutylene Using AlCl3OBu2 as a Co-initiator: Synthesis of Highly Reactive Polyisobutylene//  Macromolecules. 2010. Vol. 43. P.5503-5507.
  18. Piskun A.Yu., Vasilenko I.V., Kostjuk S.V., Zaitsev K.V., Zaitseva G.S.; Karlov S.S. Titanium Complexes of Dialkanolamine Ligands as Initiators for Living Ring-Opening Polymerization of ε-Caprolactone//  J. Polym. Sci. Part A: Polym. Chem. 2010, Vol.48. P.1230-1240.
  19. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I. Process for preparing high-reactivity isobutene homo- or copolymers., RU Patent 2555400
  20. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,637,619
  21. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,349,977
  22. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers. EP2536768.
  23. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers.WO2011101281.
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