Костюк Сергей Викторович

EN | RU

Заведующий лабораторией
Доктор химических наук
Профессор

Подразделение: Лаборатория катализа полимеризационных процессов
e-mail: kostjuks@bsu.by
Р./тел.: +375 (17) 209-51-75

 

 

  • h-index (Scopus): 23
  • h-index (Web of Science): 22
  • h-index (РИНЦ): 22
  • h-index (Google scholar): 27

(https://scholar.google.com/citations?user=x6rmcYEAAAAJ&hl=en )

Образование

  • 1994–1999  обучение на химическом факультете БГУ, окончил с красным дипломом;
  • 1999–2002: обучение в аспирантуре БГУ;
  • Декабрь 2002: защитил кандидатскую диссертацию на тему: “Живая” катионная полимеризация стирола в присутствии электронодонорных соединений (специальность 02.00.06 – высокомолекулярные соединения);
  • Октябрь 2018: защитил докторскую диссертацию на тему: Дизайн новых каталитических систем для катионной полимеризации виниловых мономеров (специальность 02.00.06 – высокомолекулярные соединения).

Карьера

  • 1999–2003: м.н.с. лаборатории химической физики и модификации целлюлозы;
  • 2003–2005: н.с. лаборатории химической физики и модификации целлюлозы;
  • 2005–2008: c.н.с. лаборатории химической физики и модификации целлюлозы;
  • с 2008: заведующий лабораторией катализа полимеризационных процессов
  • c 2018: заведующий кафедрой высокомолекулярных соединений химического факультета БГУ.

Научные интересы

Синтез полимеров методами традиционной и контролируемой катионной, анионной, радикальной и координационной полимеризации; катионная полимеризация в водных средах.

Достижения

  • 2006-2007: грант NATO научного обмена между странами восточной Европы и Францией.
  • 2007-2008: грант INTAS для молодых ученых (Франция).
  • 2010 и 2021 – Победитель конкурса на лучшего руководителя и организатора НИР студентов и аспирантов БГУ в номинации за индивидуальное руководство НИР студентов.
  • В 2014 году выступал как приглашенный лектор в Каунаском технологическом институте (Каунас, Литва).
  • В 2016 году выступал как приглашенный лектор в Zhejiang Shuren University (Ханчжоу, Китай).
  • В 2019 году выступал как приглашенный профессор в Shandong University (Цзинань, Китай).
  • Член редакционной коллеги журналов Polymers (MDPI), Macromol (MDPI) и J. Macromol. Sci. Part A; Pure Appl. Chem (Taylor & Francis).
  • Подготовил 4 кандидатов наук и более 10 магистров.

Разработки

  • Технология получения нефтеполимерных смол каталитическим методом. Патент Российской Федерации № 2057764, Патент Республики Беларусь  № 2311.
  • Технология получения нефтяного полимеризата каталитическим методом. ТУ РБ 05568283.017-99
  • Металлизирующий состав КХМ50ГФАМ.

Избранные публикации:

  1. Berezianko I.A., Nikishau P.A., Vasilenko I.V., Kostjuk S.V. Liquid coordination complexes as a new class of catalysts for the synthesis of highly reactive polyisobutylene. Polymer. 2021, 226, 123825.
  2. Prudnikau A., Shiman D.I., Ksendzov E., Harwell J., Bolotina E.A., Nikishau P.A., Kostjuk S.V., Samuel I.D.W., Lesnyak V. Design of Cross-Linked Polyisobutylene Matrix for Efficient Encapsulation of Quantum Dots. Nanoscale Adv. 2021, 3(5), 1443–1454.
  3. Shavkuta B., Bardakova K., Khristidis Y., Minaev N.V., Frolova A., Kotova S., Aksenova N., Heydari Z., Semenova E., Khlebnikova T., Golubeva E.N., Kostjuk S. Approach to tune drug release in particles fabricated from methacrylate functionalized polylactides. Molecular Systems Design and Engineering. 2021, 6(3), 202.
  4. Hulnik M.I., Kuharenko O.V., Vasilenko I.V., Timashev P., Kostjuk S.V. Quasiliving Cationic Polymerization of Anethole: Accessing High-Performance Plastic from the Biomass-Derived Monomer. ACS Sustainable Chem. Eng. 2021, 9(19), 6841–6854.
  5. Rozentsvet, V.A., Sablina, N.A., Ulyanova, D.M., Kostjuk, S.V., Tolstoy, P.M. Structure of terminal units of polybutadiene synthesized via anionic mechanism. Polym. Bull. 2021.
  6. Chumakova N.A., Golubeva E.N., Kuzin S.V., Ivanova T.A., Grigoriev I.A., Kostjuk S.V., Melnikov M.Ya. New insight into the mechanism of drug release from poly(D,l-lactide) film by electron paramagnetic resonance. Polymers. 2020, 12(12), 3046.
  7. Rezvova M.A., Yuzhalin A.E., GlushkovaT.V., Makarevich M.I., Nikishau P.A., Kostjuk S.V., Klyshnikov K.Yu., Matveeva V.G., Khanova M.Yu., Ovcharenko  E.A. Biocompatible Nanocomposites Based on Poly(styrene-block-isobutylene-block-styrene) and Carbon Nanotubes for Biomedical Applicatio. Polymers. 2020, 12, 2158.
  8. Rozentsvet V.A., Sablina N.A.,  Ulyanova D.M., Kuznetsova M.G., Kostjuk S.V., Tolstoy P.M.  A New Approach towards Investigation of Structure of Terminal units of  Poly (1,3-pentadiene) using T2-filtered NMR Spectroscopy. Macromol. Chem. Phys. 2020, 221(17).
  9. Vaitusionak A.A., Vasilenko I.V., Sych G., Kashina A.V., Simokaitiene J., Grazulevicius J.V., Kostjuk S.V.Atom-transfer radical homo- and copolymerization of carbazole-substituted styrene and perfluorostyrene. Eur. Polym. J. 2020, 134: 109843.
  10. Goswami K.G.. Mete S., Chaudhury S.S., Sar P., Ksendzov E., Mukhopadhyay C.D., Kostjuk S.V.,  De P. Self-Assembly of Amphiphilic Copolymers with Sequence Controlled Alternating Hydrophilic-Hydrophobic Pendant Side Chains. ACS Appl. Polym. Mater. 2020, 2(5), 2035-2045.
  11. Kostjuk S.V. Controlled cationic polymerization of p-methoxystyrene co-initiated by B(C6F5)3: effect of electron donor and proton trap. Eur. Polym. J. 2020, 129, 109632.
  12. Bardakova K., Moldagazyyeva Z., Krupinov G., Churbanov S., Minaev N., Timashev P., Kostjuk S.V. Tailoring the Collagen Film Structural Properties via Direct Laser Crosslinking of Star-Shaped Polylactide for Robust Scaffold Formation. Mater. Sci. Eng. C. 2020, 107, 110300.
  13. Епифанов  Е.О., Тимашев П.С., Фалетров Я.В., Пискун Ю.А., Костюк С.В., Минаев Н.В., Бардакова К.Н. 3D-Печать тетрафункционального полилактида с использованием производных ципрофлоксацина в качестве фотоинициаторов. Известия РАН. Сер.физ. 2020, 84(11), 1652–1656.
  14. Rezvova M.A., Glushkova T.V., Makarevich M.I., Nikishau P.A., Kostjuk S.V., Klyshnikov K.Yu., OvcharenkoE.A. Nanocomposites Based on Biocompatible Thermoelastoplastic and Carbon Nanoparticles for Use in Cardiovascular Surgery. Russ. J. Appl. Chem. 2020, 93(9), 1412–1420.
  15. Костюк  С.В. Комплексы хлоридов алюминия, железа(III) и галлия(III) с простыми эфирами в синтезе реакционноспособного полиизобутилена. Журн. БГУ. Химия. 2020, 2, 50–62.
  16. Kostjuk  S.V. Сopolymerization of d,l-lactide and ε-caprolactone using tin(ii) octanoate as catalysts: an insight into copolymer microstructure. J. BSU. Chemistry. 2020, 2, 43–49.
  17. Гульник М.И., Кухаренко О.В., Костюк С.В.Катионная полимеризация β-пинена в присутствии алюминийорганических соединений в качестве катализаторов. Журн. БГУ. Химия. 2020, 2, 98–107.
  18. Kostjuk S.V. Cationic step-growth polymerization of 2-methoxybenzyl alcohol using different Lewis acids as catalysts. Свиридовские чтения. 2020, 16, 89–97.
  19. Ovcharenko E., Rezvova M., Nikishau P., Kostjuk S., Glushkova T.,  Antonova L., Akentieva T., Shishkova D., Krivikina E., Klyshnikov K., Kudryavtseva Y., Barbarash L. Polyisobutylene-Based Thermoplastic Elastomers for Manufacturing Polymeric Heart Valve Leaflets: in vitro and in vivo Results. Applied Sciences. 2019, 9, 4773.
  20. Mete S., Goswami K. G., Ksendzov E., Kostjuk S. V., De P. Modulation of Side Chain Crystallinity in Strictly Alternating Copolymers. Polym. Chem. 2019, 48(10), 6588-6599.
  21. Shiman D.I., Vasilenko I.V., Kostjuk S.V. Alkoxy Aluminum Chlorides in the Cationic Polymerization of Isobutylene: Co-Initiator, Carbocation Stabilizer and Chain-Transfer Agent. Polym. Chem. 2019, 10, 5998–6002.
  22. Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene Co-Initiated by Chloroferrate Imidazole-Based Ionic Liquid: Effect of Initiator and Aromatic Compounds. Eur. Polym. J. 2019, 121, 109307.
  23. Shiman D.I., Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Cationic Polymerization of Isobutylene and C4 Mixed Feed Using Complexes of Lewis Acids with Ethers: a Comparative Study. Chinese J. Polym. Sci. 2019, 37, 891–897.
  24. Vaitusionak A.A., Vasilenko I.V., Jatautiene E, Simokaitiene J., Tomkeviciene A., Ostrauskaite J., Grazulevicius,J.V., Kostjuk S.V. Organocatalytic Controlled Anionic Ring-Opening Polymerization of Carbazole-Containing Thiiranes. Eur. Polym. J. 2019, 117, 179–187.
  25. Shiman D.I., Sayevich, V., Meerbach C., Nikishau P.A., Vasilenko I.V., Gaponik N., Kostjuk S.V., Lesnyak V. Robust Polymer Matrix Based on Isobutylene (Co)Polymers for Efficient Encapsulation of Colloidal Semiconductor Nanocrystals. ACS Appl. Nano Mater. 2019, 2, 956–963.
  26. Rezvova M.A., Ovcharenko E.A., Nikishev P.A., Kostyuk S. V., Glushkova T.V., Trebushat D.V., Chernonosova V.S., Shevelev G. Yu.,  Klyshnikov K.Yu., Kudryavtseva Yu.A., Barabash L. S. Prospects for Using Styrene-Isobutylene-Styrene (SIBS) Triblock Copolymer as a Cusp Material for Leaflet Heart Valve Prostheses: Evaluation of Physicochemical and Mechanical Properties. Russ. J Appl. Chem. 2019, 92(1), 9–19.
  27. Никишев П.А., Ксендзов Е.А., Шиман Д.И., Гапоник Л.В., Костюк С.В.. Синтез функционализированного полиизобутилена и его блок-сополимеров с D,L-лактидом Журн. БГУ. Химия. 2019, 2, 40–50.
  28. Костюк С.В. «Зеленая» катионная полимеризация: катионная полимеризация в водных средах. Полимерные материалы и технологии. 2019, 5(4), 59–63.
  29. Hulnik M.I., Vasilenko I.V., Radchenko A.V., Peruch F., Ganachaud F., Kostjuk S.V. Aqueous cationic homo- and co-polymerizations of b-myrcene and styrene: a green route toward terpene-based sustainable elastomers. Polym. Chem. 2018, 9, 5690–5700.
  30. Antipova T.V., Zhelifonova V.P., Zaitsev K.V., Nedorezova P.M., Aladyshev A.M., Klyamkina A.N., Kostyuk S.V., Danilogorskaya A.A., Kozlovsky A.G. Biodegradation of Poly-ε-caprolactones and Poly-L-lactides by Fungi. J. Polymers and the Environment. 2018, 26, 4350–4359.
  31. Appiah-Ntiamoah R., Kim H., Gadisa B.T., Baye A.F., Abebe M.W., Kostjuk S.V. Degradation kinetics of polyanethole: A newly synthesized green polymer. Mater. Chem. and Phys. 2018, 219, 468‑477.
  32. Berezianko I.A., Vasilenko I.V., Kostjuk S.V. Acidic Imidazole-Based Ionic Liquids in the Presence of Diisopropyl Ether as Catalysts for the Synthesis of Highly Reactive Polyisobutylene: Effect of Ionic Liquid Nature, Catalyst Aging, and Sonication. Polymer. 2018, 145, 382–390.
  33. Rozentsvet V.A., Kozlov V.G., Stotskaya O.A., Sablina N.A., Peruch F., Kostjuk S.V. Cationic polymerization of isoprene using CF3COOD/TiCl4 initiating system: a new view on the polymerization mechanism. Eur. Polym. J. 2018, 103, 11–20.
  34. Rozentsvet V.A., Stotskaya J.A., Ivanova V.P., Kuznetsova M.G., Tolstoy P.M., Kostjuk S.V. Structural characterization of polybutadiene synthesized via cationic mechanism. J. Polym. Sci. Part A: Polym. Chem. 2018, 56, 387–398.
  35. Bardakova K.N., Grebenik E.A., Istranova E.V., Istranov L. P., Gerasimo, Yu.V., Grosheva A.G., Zharikova T. M., Minaev N.V., Shavkuta B S., Dudova D.S., Kostyuk S. V., Vorob’eva N.N., Bagratashvili V.N., Timashev P.S, Chailakhyan R.K. Reinforced Hybrid Collagen Sponges for Tissue Engineering. Cell Technologies in Biology and Medicine. 2018, 164, 142–147. [Kletochnye Tekhnologii v Biologii i Meditsine. 2018, 1, 31–37. in Russian].
  36. Vasilenko I.V., Vaitusionak A.A., Sutaite J., Tomkeviciene A., Ostrauskaite J., Grazulevicius J.V., Kostjuk S.V. Simultaneous Step-Growth and Chain-Growth Cationic Polymerization of Styrenic Monomers Bearing Carbozolyl Groups. Polymer. 2017, 129, 83–91.
  37. Kuznetsova D, Timashev P., Ageykin A., Korolev A., Deiwick A., Shpichka A., Solovieva A., Kostjuk S., Meleshina A., Rodimova S., Akovanceva A., Butnaru D., Frolova A., Zagaynova E., Chichkov B., Bagratashvili V., Timashev P. Surface micromorphology of cross-linked tetrafunctional polylactide scaffolds inducing vessel growth and bone formation. Biofabrication. 2017, 9, 025009. (https://doi.org/10.1088/1758-5090/aa6725)
  38. Piskun Yu. A., Vasilenko I.V., Zaitsev K.V., Oprunenko Yu. F., Kostjuk S.V. Synthesis of Functional Poly(ε-caprolactone)s via Living Ring-Opening Polymerization of ε-Caprolactone using Functionalized Aluminum Alkoxides as Initiators. Macromol. Chem. Phys. 2017, 218, 1600580.
  39. Vasilenko I.V., Nikishev P.A., Shiman D.I., Kostjuk S.V. Cationic Polymerization of Isobutylene in Toluene: Toward Well-Defined exo-Olefin Terminated Medium Molecular Weight Polyisobutylenes under Mild Conditions. Polym. Chem. 2017, 8, 1417 –1425.
  40. Rozentsvet V.A., Kozlov V.G., Sablina N.A., StotskayaO.A., Peruch F., Kostjuk S.V. A new insight into the polymerization mechanism of 1,3-dienes cationic polymerization. IV. Mechanism of unsaturation loss in the polymerization of isoprene. Polym. Chem. 2017, 8, 926–935.
  41. Simkus G., Tomkeviciene A., Volyniuk D., Kostjuk S.V., Grazulevicius J.V. Synthesis and properties of photocross-linkable carbazole dimers. React. Funct. Polym. 2017, 110, 47–54.
  42. Keruckiene R., Volyniuk D., Ostrauskaite J., Peciulyte L., Grazulevicius J.V., Kostjuk S.V., Lazauskas A. Derivatives of 2-phenylindole and carbazole as host materials for phosphorescent organic light emitting diodes. Dyes Pigm. 2017, 137, 58–68.
  43. Никишев П.А., Пискун Ю.А., Василенко И.В., Гапоник Л.В., Тимашев П.С., Аковантцева А.А., Костюк С.В. Синтез блок-сополимеров стирола с D,L-лактидом методами последовательной контролируемой катионной полимеризации и анионной полимеризации с раскрытием цикла. Высокомолекулярные соединения. Серия Б. 2017, 59(6), 413–423.
  44. Meleshko T. K., Kashina A. V., Saprykina N. N., Kostyuk S. V., Vasilenko I. V., Nikishev P. A., Yakimanski A. V. Synthesis and morphology of polycaprolactone–block-polyimide–block-polycaprolactone triblock copolymers for film separation membranes. Russ. J. Appl. Chem. 2017, 90, 602−612.
  45. Vasilenko I.V.; Berezianko I.A.; Shiman, D.I.; Kostjuk, S.V. New Catalyst for the Synthesis of Highly Reactive Polyisobutylene: Chloroaluminate Imidazole-Based Ionic Liquid in the Presence of Diisopropyl Ether. Polym. Chem., 2016, 7, 5615–5619.
  46. Shiman, D.I.; Vasilenko, I.V.; Kostjuk, S.V. Cationic Polymerization of Isobutylene Catalyzed by iBuAlCl2 in the Presence of Ethers: Effect of Catalyst Pre-Activation and Mixture of Two Ethers. Polymer, 2016, 99, 633–641.
  47. Rozentsvet, V.A.; Kozlov, V.G.; Korovina, N.A.; Stotskaya, O.A.; Gnezdilov, O.I.; Kostjuk, S.V. The Structure of Cationic Polyisoprene: Branching versus Cyclization. Macromol. Chem. Phys., 2016, 217(16), 1860–1867.
  48. Rozentsvet V.A., Korovina, N.A.; Stotskaya, O.A.; Kuznetsova, M.G.; Peruch, F.; Kostjuk, S.V. Comprehensive Structural Characterization of Polyisoprene Synthesized via Cationic Mechanism. J. Polym. Sci. Part A: Polym. Chem., 2016, 54(15), 2430–2442.
  49. Vasilenko, I.V.; Ganachaud, F.; Kostjuk, S.V. New Insights in the Cationic Polymerization in Emulsion Catalyzed by Water-Dispersible Lewis Acid Surfactant Complexes: A Case Study with p-Methoxystyrene. Macromolecules, 2016, 49(9), 3264–3273.
  50. Timashev, P.; Kuznetsova, D.; Koroleva, A.; Prodanets, N.; Deiwick, A.; Piskun, Yu.; Bardakova, K.; Dzhoyashvili, N; Kostjuk, S.; Zagaynova, E.; Rochev, Y.; Chichkov, B.; Bagratashvili, V. Novel biodegradable star-shaped polylactide scaffolds for bone regeneration fabricated by two-photon polymerization. Nanomedicine, 2016, 11(9), 1041‑1053.
  51. Vasilenko, I.V.; Yeong, H.Y.; Delgado, M.; Ouardad, S.; Peruch, F.; Voit, B.; Ganachaud, F.; Kostjuk, S.V. A catalyst platform for unique cationic (co)polymerization in aqueous emulsion. Angew. Chem. Int. Ed., 2015, 54(43), 12728–12723.
  52. Ouardad, S.; Wirotius, A.-L.; Kostjuk S.V.; Ganachaud, F.; Peruch, F. Carbocationic polymerization of isoprene using cumyl initiators: progress in understanding the side reactions. RSC Advances, 2015, 5(73), 59218–59225.
  53. Piskun, Yu.A., Vasilenko, I.V., Zaitsev, K.V., Karlov S.S., Zaitseva G.S., Gaponik L.V., Kostjuk S.V. Controlled homo- and copolymerization of e-caprolactone and D,L-lactide by titanium (IV) complexes. Russ. Chem. Bull., 2015, 64(1), 181–188.
  54. Kostjuk S.V.; Vasilenko, I.V.; Shiman, D.I.; Frolov, A.N.; Gaponik, L.V. Highly Reactive Polyisobutylenes via Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-polar Media: Scope and Limitations. Macromol. Symp., 2015, 349(1), 94–103.
  55. Kostjuk, S.V. Recent progress in the Lewis acids co-initiated cationic polymerization of isobutylene and 1,3-dienes. RSC Advances, 2015, 5(17), 13125–13144.
  56. Shiman, D.I.; Vasilenko, I.V.; Kostjuk S.V. Cationic Polymerization of Isobutylene by Complexes of Alkylaluminum Dichlorides with Diisopropyl Ether: An Activating Effect of Water. J. Polym. Sci. Part A: Polym. Chem., 2014, 52(16), 2386–2393.
  57. Rozentsvet, V.A.; Kozlov, V.A.; Korovina, N.A.; Novakov, I.A.; Kostjuk, S.V. A New Insight into the Mechanism of 1,3-Dienes Cationic Polymerization. III: Polymerization of 1,3-pentadiene with CF3COOD/TiCl4 initiating system: chain end structure and kinetics. Macromol. Chem. Phys., 2014, 215(12), 1239–1249.
  58. Vasilenko, I.V.; Shiman, D.I.; Kostjuk S.V. Alkylaluminum dichloride–ether complexes which are fully soluble in hydrocarbons as catalysts for the synthesis of exo-olefin terminated polyisobutylene at room temperature. Polym. Chem., 2014, 5(12), 3855–3866.
  59. Zaitsev, K.V.; Piskun, Yu.A.; Oprunenko, Y.F.; Karlov, S.S.; Zaitseva, G.S.; Vasilenko, I.V.; Churakov, A.V.; Kostjuk, S.V. Controlled Ring-Opening Homo- and Copolymerization of e-Caprolactone and D,L-Lactide by Iminophenolate Aluminum Complexes: An Efficient Approach Towards Well-Defined Macromonomers. J. Polym. Sci. Part A: Polym. Chem., 2014, 52(9), 1237–1250.
  60. Jadhav, A.H.; Chinnappan, A.; Patil, R.P.; Kostjuk, S.V.; Kim, H. Green chemical conversion of fructose into 5-hydroxymethylfurfural (HMF) using unsymmetrical dicationic ionic liquids under mild reaction condition. Chemical Engineering Journal, 2014, 243, 92–98.
  61. Rozentsvet, V.A.; Kozlov, V.G.; Korovina, N.A.; Kostjuk, S.V. A New Insight into the Mechanism of 1,3-Dienes Cationic Polymerization. I. Polymerization of 1,3-Pentadiene with tBuCl/TiCl4 Initiating System: Kinetic and Mechanistic Study. Macromol. Chem. Phys., 2013, 214(23), 2694–2704.
  62. Rozentsvet, V.A.; Korovina, N.A.; Ivanova, V.P.; Kuznetsova, M.G.; Kostjuk, S.V. A New Insight into the Mechanism of 1,3-Dienes Cationic Polymerization. II. Structure of Poly(1,3-pentadiene) Synthesized with tBuCl/TiCl4 Initiating System. J. Polym. Sci. Part A: Polym. Chem., 2013, 51(15), 3297–3307.
  63. Rozentsvet, V.A.; Kozlov, V.G.; Ziganshina, E.F.; Boreiko, N.P.; Kostjuk, S.V. Cationic Polymerization of Isoprene using Zinc Halides as Co-initiators: Toward well-defined oligo(isoprene)s under mild conditions. Polym. Int. 2013, 62(5), 817–826.
  64. Shiman, D.I.; Vasilenko, I.V.; Kostjuk, S.V. Cationic Polymerization of Isobutylene by AlCl3/Ether Complexes in Non-Polar Solvents: Effect of Ether Structure on the Selectivity of b-H Elimination. Polymer 2013, 54(9), 2235–2242.
  65. Radchenko, A.V.; Kostjuk, S.V.; Ganachaud, F. Cationic Polymerization of Isobutyl Vinyl Ether in Aqueous Media: Physicochemical Tricks to Fight against Thermal Runaway. Polym. Chem. 2013, 4(6), 1883–1892.
  66. Rozentsvet, V.A.; Kozlov, V.G.; Korovina, N.A.; Ivanova, V.P.; Kostjuk, S.V. Cationic Polymerization of 1,3-Pentadiene Co-initiated by Zinc Halides. J. Appl. Polym. Sci., 2013 128(3), 1771–1778.
  67. Kostjuk, S.V.; Yeong, H.Y.; Voit, B. Cationic Polymerization of Isobutylene at Room Temperature. J. Polym. Sci. Part A: Polym. Chem., 2013, 51(3), 471–486.
  68. Ouardad, S.; Bakleh, M-E.; Kostjuk, S.V.; Ganachaud, F.; Puskas, J.E.; Deffieux, A.; Peruch, F. Bio-inspired Cationic Polymerization of Isoprene and Analogues: the Current Situation. Polym. Int., 2012, 61(2), 149–156.
  69. Vasilenko, I.V.; Shiman, D.I.; Kostjuk, S.V. Highly Reactive Polyisobutylenes via AlCl3OBu2-Coinitiated Cationic Polymerization of Isobutylene: Effect of Solvent Polarity, Temperature, and Initiator. J. Polym. Sci. Part A: Polym. Chem., 2012, 50(4), 750–758.
  70. Piskun, Yu.A.; Vasilenko, I.V.; Gaponik L.V.; Kostjuk, S.V. Activated Anionic Ring-opening Polymerization of ε-Caprolactam with Magnesium Di(ε-caprolactamate) as Initiator: Effect of Magnesium Halides. Polym. Bull., 2012, 68, 1501–1513.
  71. Kostjuk, S.V.; Ganachaud, F.; Radchenko, A.V.; Vasilenko, I.V. Cationic Polymerization of Styrene Derivatives and Cyclopentadiene Catalyzed by B(C6F5)3 in Aqueous Media: Comparison of Suspension, Emulsion and Dispersion Processes. Macromol. Symp., 2011, 308(1), 1–7.
  72. Ouardad, S.; Kostjuk, S.V.; Ganachaud, F.; Puskas, J.E.; Deffieux, A.; Peruch, F. Cationation of Dimethylallyl Alcohols by B(C6F5)3 as Models of the (re)Initiation Reaction in the Bio-inspired Cationic Polymerization of Isoprene. J. Polym. Sci. Part A: Polym. Chem., 2011, 49(23), 4948–4954.
  73. Kukhta, N.A.; Vasilenko, I.V.; Kostjuk, S.V. Room Temperature Cationic Polymerization of b-Pinene using Modified AlCl3 Catalyst: Toward Sustainable Plastics from Renewable Biomass Resources. Green Chem. 2011, 13(9), 2362‑2364.
  74. Kostjuk, S.V.; Ouardad, S.; Peruch, F.; Deffieux, A.; Absalon, C.; Puskas, J.E.; Ganachaud, F. Carbocationic Polymerization of Isoprene Co-initiated by B(C6F5)3: An Alternative Route Towards Natural Rubber Polymer Analogues? Macromolecules 2011, 44(6), 1372–1384.
  75. Frolov, A.N.; Kostjuk, S.V.; Vasilenko, I.V.; Kaputsky, F.N. Controlled Cationic Polymerization of Styrene Using AlCl3OBu2 as a Co-initiator: Towards High Molecular Weight Polystyrenes at Elevated Temperatures. J. Polym. Sci. Part A: Polym. Chem. 2010, 48(17), 3736‑3743.
  76. Vasilenko, I.V.; Frolov, A.N.; Kostjuk, S.V. Cationic Polymerization of Isobutylene Using AlCl3OBu2 as a Co-initiator: Synthesis of Highly Reactive Polyisobutylene. Macromolecules 2010, 43(13), 5503‑5507.
  77. Kostjuk, S.V.; Ganachaud, F. Cationic Polymerization of Vinyl Monomers in Aqueous Media: From Monofunctional Oligomers to Long-Lived Polymer Chains. Accounts of Chemical Research 2010, 43(3), 357‑367.
  78. Piskun, A.Yu.; Vasilenko, I.V.; Kostjuk, S.V.; Zaitsev, K.V.; Zaitseva, G.S.; Karlov, S.S. Titanium Complexes of Dialkanolamine Ligands as Initiators for Living Ring-Opening Polymerization of ε-Caprolactone. J. Polym. Sci. Part A: Polym. Chem. 2010, 48(5), 1230‑1240.
  79. Kostjuk, S.V.; Ortega, E.; Ganachaud, F.; Ameduri, B.; Boutevin, B. Anionic Ring–opening Polymerization of Hexafluoropropylene Oxide using Alkali Metal Fluorides as Catalysts: a Mechanistic Study. Macromolecules 2009, 42(3), 612‑619.
  80. Kostjuk, S.V.; Radchenko, A.V.; Ganachaud F. Controlled cationic polymerization of cyclopentadiene with B(C6F5)3 as a coinitiator in the presence of water. J. Polym. Sci. Part A: Polym. Chem. 2008, 46(14), 4734‑4747.
  81. Radchenko, A.V.; Kostjuk, S.V.; Vasilenko, I.V.; Ganachaud, F.; Kaputsky, F.N.; Guillaneuf, Y. Kinetic study on the living/controlled cationic polymerization of p-methoxystyrene coinitiated by tris(pentafluorophenyl)borane. J. Polym. Sci. Part A: Polym. Chem. 2008, 46(20), 6928‑6939.
  82. Radchenko, A.V.; Kostjuk S.V.; Vasilenko I.V.; Ganachaud F.; Kaputsky F.N. Controlled/living cationic polymerization of styrene with BF3OEt2 as coinitiator in the presence of water: improvements and limitations. Eur. Polym. J. 2007, 43(6), 2576‑2583.
  83. Kostjuk, S.V.; Radchenko, A.V.; Ganachaud, F. Controlled/living cationic polymerization of p-methoxystyrene in solution and aqueous dispersion using tris(pentafluorophenyl)borane as a Lewis acid: acetonitrile does the job. Macromolecules 2007, 40(3), 482‑490.
  84. Kostjuk, S.V.; Dubovik, A.Yu.; Vasilenko, I.V.; Frolov, A.N.; Kaputsky, F.N. Kinetic and mechanistic study of the quasiliving cationic polymerization of styrene in the 2-phenyl-2-propanol/AlCl3OBu2 initiating system. Eur. Polym. J. 2007, 43(3), 968‑979.
  85. Kostjuk, S.V.; Ganachaud, F. Cationic polymerization of styrene in solution and aqueous suspension using B(C6F5)3 as a water-tolerant Lewis acid. Macromolecules 2006, 39(9), 3110‑3113.

Патенты

  1. Corberan Roc, R.; Muehlbach K.; Wettlings T.; Kostjuk S.V.; Vasilenko I.V.; Shiman D.I. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 2019/0062472 A1
  2. Corberan Roc, R.; Muehlbach K.; Wettlings T.; Kostjuk S.V.; Vasilenko I.V.; Shiman D.I., Berezianka I. Process for preparing high-reactivity isobutene homo- or copolymers. WO 2018/015306 A1
  3. Corberan Roc, R.; Muehlbach K.; Wettlings T.; Kostjuk S.V.; Vasilenko I.V.; Shiman D.I. Process for preparing high-reactivity isobutene homo- or copolymers. WO 2017/140602 A1
  4. Corberan Roc, R.; Muehlbach K.; Wettlings T.; Kostjuk S.V.; Vasilenko I.V.; Shiman D.I. Process for preparing high-reactivity isobutene homo- or copolymers. WO 2017/140603 A1
  5. Ganachaud, F.; Kostjuk, S.V.; Delgado, M. Process for preparing a polymer by cationic polymerization of a hydrophobic monomer in aqueous dispersion. WO 2016/135411 A1
  6. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I. Process for preparing high-reactivity isobutene homo- or copolymers., RU Patent 2555400.
  7. Pierrick, B.; Boucheteau, T.; Ghislain, D.; Ganachaud, F. ; Kostjuk, S.V. Specific phosphonated copolymers and inorganic particles grafted by said copolymers. US Patent 2014/0113215 A1.
  8. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,637,619
  9. Pierrick, B.; Boucheteau, T.; Ghislain, D.; Ganachaud, F. ; Kostjuk, S.V. Copolymeres phosphones specifiques et particules inorganiques greffees lesdits copolymeres. FR 2974091 A1.
  10. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Process for preparing high-reactivity isobutene homo- or copolymers. US Patent 8,349,977
  11. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers. EP2536768.
  12. König, H. M.; Mühlbach, K; Kiefer, M.; Kostjuk, S.V.; Vasilenko, I.; Frolov, A. Method for producing highly reactive isobutylene homo or copolymers. WO2011101281.
  13. Kaputsky, F.N.; Mardykin, V.P.; Gaponik, L.V.; Lesnyak, V.P.; Kostjuk S.V. et al. BY Patent № 6489 May 19‚ 2004